Selective oxidation of glycerol to dihydroxyacetone over a Pd-Ag catalyst

Shota Hirasawa; Yoshinao Nakagawa; Keiichi Tomishige

doi:10.1039/c2cy20062g

Selective oxidation of glycerol to dihydroxyacetone over a Pd-Ag catalyst

Shota Hirasawa, Yoshinao Nakagawa, Keiichi Tomishige

ENG - Applied Chemistry

Tohoku University

Research output: Contribution to journal › Article › peer-review

72 Citations (Scopus)

Abstract

Glycerol oxidation with molecular oxygen was conducted using Pd-based catalysts under neutral conditions. Pd-Ag/C showed higher selectivity to dihydroxyacetone (DHA) and higher activity than Pd/C. The DHA yield reached 44% at 52% glycerol conversion over Pd-Ag/C (Ag/Pd = 1). The Pd-Ag alloy phase is responsible for the high activity and DHA selectivity.

Original language	English
Pages (from-to)	1150-1152
Number of pages	3
Journal	Catalysis Science and Technology
Volume	2
Issue number	6
DOIs	https://doi.org/10.1039/c2cy20062g
Publication status	Published - 2012 Jun

Access to Document

10.1039/c2cy20062g

Cite this

@article{854d14453e6d49dbbb7d37d6c936c1ec,

title = "Selective oxidation of glycerol to dihydroxyacetone over a Pd-Ag catalyst",

abstract = "Glycerol oxidation with molecular oxygen was conducted using Pd-based catalysts under neutral conditions. Pd-Ag/C showed higher selectivity to dihydroxyacetone (DHA) and higher activity than Pd/C. The DHA yield reached 44% at 52% glycerol conversion over Pd-Ag/C (Ag/Pd = 1). The Pd-Ag alloy phase is responsible for the high activity and DHA selectivity.",

author = "Shota Hirasawa and Yoshinao Nakagawa and Keiichi Tomishige",

year = "2012",

month = jun,

doi = "10.1039/c2cy20062g",

language = "English",

volume = "2",

pages = "1150--1152",

journal = "Catalysis Science and Technology",

issn = "2044-4753",

publisher = "Royal Society of Chemistry",

number = "6",

}

TY - JOUR

T1 - Selective oxidation of glycerol to dihydroxyacetone over a Pd-Ag catalyst

AU - Hirasawa, Shota

AU - Nakagawa, Yoshinao

AU - Tomishige, Keiichi

PY - 2012/6

Y1 - 2012/6

N2 - Glycerol oxidation with molecular oxygen was conducted using Pd-based catalysts under neutral conditions. Pd-Ag/C showed higher selectivity to dihydroxyacetone (DHA) and higher activity than Pd/C. The DHA yield reached 44% at 52% glycerol conversion over Pd-Ag/C (Ag/Pd = 1). The Pd-Ag alloy phase is responsible for the high activity and DHA selectivity.

AB - Glycerol oxidation with molecular oxygen was conducted using Pd-based catalysts under neutral conditions. Pd-Ag/C showed higher selectivity to dihydroxyacetone (DHA) and higher activity than Pd/C. The DHA yield reached 44% at 52% glycerol conversion over Pd-Ag/C (Ag/Pd = 1). The Pd-Ag alloy phase is responsible for the high activity and DHA selectivity.

UR - http://www.scopus.com/inward/record.url?scp=84861395606&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84861395606&partnerID=8YFLogxK

U2 - 10.1039/c2cy20062g

DO - 10.1039/c2cy20062g

M3 - Article

AN - SCOPUS:84861395606

SN - 2044-4753

VL - 2

SP - 1150

EP - 1152

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

IS - 6

ER -

Selective oxidation of glycerol to dihydroxyacetone over a Pd-Ag catalyst

Abstract

Access to Document

Other files and links

Fingerprint

Cite this