Selective separation and recovery of cesium by ammonium tungstophosphate-alginate microcapsules

Hitoshi Mimura, Yan Wu, Wang Yufei, Yuichi Niibori, Isao Yamagishi, Masaki Ozawa, Takashi Ohnishi, Shinichi Koyama

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22 Citations (Scopus)


A fine crystalline ammonium tungstophosphate (AWP) exchanger with high selectivity towards Cs+ was encapsulated in biopolymer matrices (calcium alginate, CaALG). The characterization of the AWP-CaALG microcapsule was examined using SEM/WDS, IR and DTA/TG analyses, and the selective separation and recovery of 137Cs were examined by the batch and column methods using simulated (SHLLW) and real high-level liquid waste (HLLW). The free energy (ΔG°) of the ion exchange (NH4+ ↔ Cs +) for fine AWP crystals was determined at -13.2 kJ/mol, indicating the high selectivity of AWP towards Cs+. Spherical and elastic AWP-CaALG microcapsules (∼700 μm in diameter) were obtained and fine AWP crystals were uniformly immobilized in alginate matrices. Relatively large Kd values of Cs+ above 105 cm3/g were obtained in the presence of 10-3-1 M Ca(NO3) 2, resulting in a separation factor of Cs/Rb exceeding 10 2. The irradiated samples (60Co, 17.6 kGy) also exhibited large Kd values exceeding 105 cm3/g in the presence of 2.5 M HNO3. The Kd values in the presence of 0.1-9 M HNO3 for 67 elements were determined and the order of K d value was Cs+ Rb+ > Ag+. The breakthrough curve of Cs+ had an S-shaped profile, and the breakpoint increased with decreasing flow rate; the breakpoint and breakthrough capacity at a flow rate of 0.35 cm3/min for the column (0.7 g AWP-CaALG) were estimated at 25.2 cm3 and 0.068 mmol/g, respectively. Good breakthrough and elution properties were retained even after thrice-repeated runs. The uptake (%) of Cs+ in SHLLW (28 metal components-1.92 M HNO3, SW-11, JAEA) was estimated at 97%, and the distribution of Cs+ and Zr/Ru into the AWP and alginate phases, respectively, were observed by WDS analysis. Further, the selective uptake of 137Cs exceeding 99% was confirmed by using real HLLW (FBR "JOYO", JAEA). AWP-CaALG microcapsules are thus effective for the selective separation and recovery of Cs+ from HLLWs.

Original languageEnglish
Pages (from-to)4750-4757
Number of pages8
JournalNuclear Engineering and Design
Issue number12
Publication statusPublished - 2011 Dec 1

ASJC Scopus subject areas

  • Nuclear and High Energy Physics
  • Nuclear Energy and Engineering
  • Materials Science(all)
  • Safety, Risk, Reliability and Quality
  • Waste Management and Disposal
  • Mechanical Engineering


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