Self-assembly of Pt(II) spherical complexes via temporary labilization of the metal-ligand association in 2,2,2-trifluoroethanol

Daishi Fujita; Asana Takahashi; Sota Sato; Makoto Fujita

doi:10.1021/ja2059236

Self-assembly of Pt(II) spherical complexes via temporary labilization of the metal-ligand association in 2,2,2-trifluoroethanol

Daishi Fujita, Asana Takahashi, Sota Sato, Makoto Fujita

Research output: Contribution to journal › Article › peer-review

93 Citations (Scopus)

Abstract

Thermodynamically controlled platinum(II) spherical complexes were synthesized via temporary labilization of inert Pt(II)-pyridine bonds by the addition of the strong hydrogen-bond donor 2,2,2-trifluoroethanol (TFE), which weakens the pyridine-metal interaction. The platinum complex was stably trapped after removal of TFE and showed higher acid durability than its palladium counterpart.

Original language	English
Pages (from-to)	13317-13319
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	133
Issue number	34
DOIs	https://doi.org/10.1021/ja2059236
Publication status	Published - 2011 Aug 31

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja2059236

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abstract = "Thermodynamically controlled platinum(II) spherical complexes were synthesized via temporary labilization of inert Pt(II)-pyridine bonds by the addition of the strong hydrogen-bond donor 2,2,2-trifluoroethanol (TFE), which weakens the pyridine-metal interaction. The platinum complex was stably trapped after removal of TFE and showed higher acid durability than its palladium counterpart.",

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AU - Takahashi, Asana

AU - Sato, Sota

AU - Fujita, Makoto

PY - 2011/8/31

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AB - Thermodynamically controlled platinum(II) spherical complexes were synthesized via temporary labilization of inert Pt(II)-pyridine bonds by the addition of the strong hydrogen-bond donor 2,2,2-trifluoroethanol (TFE), which weakens the pyridine-metal interaction. The platinum complex was stably trapped after removal of TFE and showed higher acid durability than its palladium counterpart.

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Self-assembly of Pt(II) spherical complexes via temporary labilization of the metal-ligand association in 2,2,2-trifluoroethanol

Abstract

ASJC Scopus subject areas

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