Self-catalysis in thermal hysteresis during random-coil to helix-dimer transition of the sulfonamidohelicene tetramer

Masanori Shigeno; Yo Kushida; Masahiko Yamaguchi

doi:10.1039/c4cc10418h

Self-catalysis in thermal hysteresis during random-coil to helix-dimer transition of the sulfonamidohelicene tetramer

Masanori Shigeno, Yo Kushida, Masahiko Yamaguchi

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

The sulfonamidohelicene tetramer changes its structure between a random-coil and a helix-dimer, by which molecular thermal hysteresis appears. Mixing experiments on helix-dimer and random-coil solutions and kinetic analysis show that the transition from the random-coil to the helix-dimer involves self-catalysis by the helix-dimer. This journal is

Original language	English
Pages (from-to)	4040-4043
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	19
DOIs	https://doi.org/10.1039/c4cc10418h
Publication status	Published - 2015 Mar 7

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Self-catalysis in thermal hysteresis during random-coil to helix-dimer transition of the sulfonamidohelicene tetramer

Abstract

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