Silyl-pyridine-amine pincer-ligated iridium complexes for catalytic silane deuteration: Via room temperature C-D bond activation of benzene- d 6

Takashi Komuro; Tomohiro Osawa; Ryuju Suzuki; Daiki Mochizuki; Hironori Higashi; Hiromi Tobita

doi:10.1039/c8cc09178a

Silyl-pyridine-amine pincer-ligated iridium complexes for catalytic silane deuteration: Via room temperature C-D bond activation of benzene- d ₆

Takashi Komuro, Tomohiro Osawa, Ryuju Suzuki, Daiki Mochizuki, Hironori Higashi, Hiromi Tobita

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Iridium-hydrido complexes bearing a hemilabile silyl-pyridine-amine pincer ligand were synthesised. They were found to catalyse Si-H deuteration of trialkylsilanes with excess benzene-d₆ in 99-94% conversion at room temperature through C-D bond activation and H/D exchange.

Original language	English
Pages (from-to)	957-960
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	7
DOIs	https://doi.org/10.1039/c8cc09178a
Publication status	Published - 2019

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/c8cc09178a

Cite this

@article{570f248355184c9eb0954207e7cbb0c5,

title = "Silyl-pyridine-amine pincer-ligated iridium complexes for catalytic silane deuteration: Via room temperature C-D bond activation of benzene- d 6",

abstract = "Iridium-hydrido complexes bearing a hemilabile silyl-pyridine-amine pincer ligand were synthesised. They were found to catalyse Si-H deuteration of trialkylsilanes with excess benzene-d6 in 99-94% conversion at room temperature through C-D bond activation and H/D exchange.",

author = "Takashi Komuro and Tomohiro Osawa and Ryuju Suzuki and Daiki Mochizuki and Hironori Higashi and Hiromi Tobita",

note = "Funding Information: This work was supported by JSPS KAKENHI grant numbers: JP16K05714, JP15H03782 and JP25410058 from the Japan Society for the Promotion of Science (JSPS). We are grateful to the Research and Analytical Center for Giant Molecules, Tohoku University for mass spectroscopic measurements and elemental analysis. Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c8cc09178a",

language = "English",

volume = "55",

pages = "957--960",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "7",

}

TY - JOUR

T1 - Silyl-pyridine-amine pincer-ligated iridium complexes for catalytic silane deuteration

T2 - Via room temperature C-D bond activation of benzene- d 6

AU - Komuro, Takashi

AU - Osawa, Tomohiro

AU - Suzuki, Ryuju

AU - Mochizuki, Daiki

AU - Higashi, Hironori

AU - Tobita, Hiromi

N1 - Funding Information: This work was supported by JSPS KAKENHI grant numbers: JP16K05714, JP15H03782 and JP25410058 from the Japan Society for the Promotion of Science (JSPS). We are grateful to the Research and Analytical Center for Giant Molecules, Tohoku University for mass spectroscopic measurements and elemental analysis. Publisher Copyright: © 2019 The Royal Society of Chemistry.

PY - 2019

Y1 - 2019

N2 - Iridium-hydrido complexes bearing a hemilabile silyl-pyridine-amine pincer ligand were synthesised. They were found to catalyse Si-H deuteration of trialkylsilanes with excess benzene-d6 in 99-94% conversion at room temperature through C-D bond activation and H/D exchange.

AB - Iridium-hydrido complexes bearing a hemilabile silyl-pyridine-amine pincer ligand were synthesised. They were found to catalyse Si-H deuteration of trialkylsilanes with excess benzene-d6 in 99-94% conversion at room temperature through C-D bond activation and H/D exchange.

UR - http://www.scopus.com/inward/record.url?scp=85060145561&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85060145561&partnerID=8YFLogxK

U2 - 10.1039/c8cc09178a

DO - 10.1039/c8cc09178a

M3 - Article

C2 - 30604784

AN - SCOPUS:85060145561

SN - 1359-7345

VL - 55

SP - 957

EP - 960

JO - Chemical Communications

JF - Chemical Communications

IS - 7

ER -

Silyl-pyridine-amine pincer-ligated iridium complexes for catalytic silane deuteration: Via room temperature C-D bond activation of benzene- d ₆

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this