Silyl(silylene) Complexes of Iron and Ruthenium

H. Tobita

doi:10.1016/B978-0-12-803530-6.00028-7

Silyl(silylene) Complexes of Iron and Ruthenium

H. Tobita

IEHE - Institute for Excellence in Higher Education (organization affiliation only)

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

Abstract

Base-free silyl(silylene) complexes of iron and ruthenium Cp*M(CO)(=SiMes₂)SiMe₃ (Cp* = η⁵-C₅Me₅, M = Fe, Ru, Mes = mesityl) can be prepared in high yields by the reaction of pyridine complexes Cp*M(CO)(NC₅H₅)Me (M = Fe, Ru) with hydrodisilane HMe₂SiSiMes₂Me at room temperature. The pyridine complexes Cp*M(CO)(NC₅H₅)Me are prepared by the photolysis of a solution of Cp*M(CO)₂Me in the presence of excess pyridine just before use. A proposed mechanism for formation of the silyl(silylene) complexes involving 1,2-silyl shift and 1,3-methyl shift is shown in Scheme 28.1.

Original language	English
Title of host publication	Efficient Methods for Preparing Silicon Compounds
Publisher	Elsevier Inc.
Pages	381-384
Number of pages	4
ISBN (Electronic)	9780128035689
ISBN (Print)	9780128035306
DOIs	https://doi.org/10.1016/B978-0-12-803530-6.00028-7
Publication status	Published - 2016 May 31

Keywords

1,2-Shift
1,3-Shift
Iron complex
Rearrangement
Ruthenium complex
Silyl complex
Silylene complex

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10.1016/B978-0-12-803530-6.00028-7

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title = "Silyl(silylene) Complexes of Iron and Ruthenium",

abstract = "Base-free silyl(silylene) complexes of iron and ruthenium Cp*M(CO)(=SiMes2)SiMe3 (Cp* = η5-C5Me5, M = Fe, Ru, Mes = mesityl) can be prepared in high yields by the reaction of pyridine complexes Cp*M(CO)(NC5H5)Me (M = Fe, Ru) with hydrodisilane HMe2SiSiMes2Me at room temperature. The pyridine complexes Cp*M(CO)(NC5H5)Me are prepared by the photolysis of a solution of Cp*M(CO)2Me in the presence of excess pyridine just before use. A proposed mechanism for formation of the silyl(silylene) complexes involving 1,2-silyl shift and 1,3-methyl shift is shown in Scheme 28.1.",

keywords = "1,2-Shift, 1,3-Shift, Iron complex, Rearrangement, Ruthenium complex, Silyl complex, Silylene complex",

author = "H. Tobita",

year = "2016",

month = may,

day = "31",

doi = "10.1016/B978-0-12-803530-6.00028-7",

language = "English",

isbn = "9780128035306",

pages = "381--384",

booktitle = "Efficient Methods for Preparing Silicon Compounds",

publisher = "Elsevier Inc.",

address = "United States",

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TY - CHAP

T1 - Silyl(silylene) Complexes of Iron and Ruthenium

AU - Tobita, H.

PY - 2016/5/31

Y1 - 2016/5/31

N2 - Base-free silyl(silylene) complexes of iron and ruthenium Cp*M(CO)(=SiMes2)SiMe3 (Cp* = η5-C5Me5, M = Fe, Ru, Mes = mesityl) can be prepared in high yields by the reaction of pyridine complexes Cp*M(CO)(NC5H5)Me (M = Fe, Ru) with hydrodisilane HMe2SiSiMes2Me at room temperature. The pyridine complexes Cp*M(CO)(NC5H5)Me are prepared by the photolysis of a solution of Cp*M(CO)2Me in the presence of excess pyridine just before use. A proposed mechanism for formation of the silyl(silylene) complexes involving 1,2-silyl shift and 1,3-methyl shift is shown in Scheme 28.1.

AB - Base-free silyl(silylene) complexes of iron and ruthenium Cp*M(CO)(=SiMes2)SiMe3 (Cp* = η5-C5Me5, M = Fe, Ru, Mes = mesityl) can be prepared in high yields by the reaction of pyridine complexes Cp*M(CO)(NC5H5)Me (M = Fe, Ru) with hydrodisilane HMe2SiSiMes2Me at room temperature. The pyridine complexes Cp*M(CO)(NC5H5)Me are prepared by the photolysis of a solution of Cp*M(CO)2Me in the presence of excess pyridine just before use. A proposed mechanism for formation of the silyl(silylene) complexes involving 1,2-silyl shift and 1,3-methyl shift is shown in Scheme 28.1.

KW - 1,2-Shift

KW - 1,3-Shift

KW - Iron complex

KW - Rearrangement

KW - Ruthenium complex

KW - Silyl complex

KW - Silylene complex

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U2 - 10.1016/B978-0-12-803530-6.00028-7

DO - 10.1016/B978-0-12-803530-6.00028-7

M3 - Chapter

AN - SCOPUS:84994101818

SN - 9780128035306

SP - 381

EP - 384

BT - Efficient Methods for Preparing Silicon Compounds

PB - Elsevier Inc.

ER -

Silyl(silylene) Complexes of Iron and Ruthenium

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Keywords

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