Single-component molecular conductor [Zn(tmdt)2] and related Zn complexes

Kimiko Yamamoto; Emiko Fujiwara; Akiko Kobayashi; Yuichi Fujishiro; Eiji Nishibori; Makoto Sakata; Masaki Takata; Hisashi Tanaka; Yoshinori Okano; Hayao Kobayashi

doi:10.1246/cl.2005.1090

Single-component molecular conductor [Zn(tmdt)₂] and related Zn complexes

Kimiko Yamamoto, Emiko Fujiwara, Akiko Kobayashi, Yuichi Fujishiro, Eiji Nishibori, Makoto Sakata, Masaki Takata, Hisashi Tanaka, Yoshinori Okano, Hayao Kobayashi

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Single-component molecular conductors based on zinc complexes with filled 3d shells and extended-TTF ligands, [ZnL₂] (L = tmdt, dmdt, and dt) were prepared. The crystal structure of semiconducting [Zn(tmdt)₂] (ρ (rt) ≈ 50 Ω cm) was determined by the synchrotron radiation X-ray powder diffraction experiments. The molecule has a tetrahedral geometry and two ligand planes are almost perpendicular to each other.

Original language	English
Pages (from-to)	1090-1091
Number of pages	2
Journal	Chemistry Letters
Volume	34
Issue number	8
DOIs	https://doi.org/10.1246/cl.2005.1090
Publication status	Published - 2005 Aug 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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title = "Single-component molecular conductor [Zn(tmdt)2] and related Zn complexes",

abstract = "Single-component molecular conductors based on zinc complexes with filled 3d shells and extended-TTF ligands, [ZnL2] (L = tmdt, dmdt, and dt) were prepared. The crystal structure of semiconducting [Zn(tmdt)2] (ρ (rt) ≈ 50 Ω cm) was determined by the synchrotron radiation X-ray powder diffraction experiments. The molecule has a tetrahedral geometry and two ligand planes are almost perpendicular to each other.",

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language = "English",

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T1 - Single-component molecular conductor [Zn(tmdt)2] and related Zn complexes

AU - Yamamoto, Kimiko

AU - Fujiwara, Emiko

AU - Kobayashi, Akiko

AU - Fujishiro, Yuichi

AU - Nishibori, Eiji

AU - Sakata, Makoto

AU - Takata, Masaki

AU - Tanaka, Hisashi

AU - Okano, Yoshinori

AU - Kobayashi, Hayao

PY - 2005/8/5

Y1 - 2005/8/5

N2 - Single-component molecular conductors based on zinc complexes with filled 3d shells and extended-TTF ligands, [ZnL2] (L = tmdt, dmdt, and dt) were prepared. The crystal structure of semiconducting [Zn(tmdt)2] (ρ (rt) ≈ 50 Ω cm) was determined by the synchrotron radiation X-ray powder diffraction experiments. The molecule has a tetrahedral geometry and two ligand planes are almost perpendicular to each other.

AB - Single-component molecular conductors based on zinc complexes with filled 3d shells and extended-TTF ligands, [ZnL2] (L = tmdt, dmdt, and dt) were prepared. The crystal structure of semiconducting [Zn(tmdt)2] (ρ (rt) ≈ 50 Ω cm) was determined by the synchrotron radiation X-ray powder diffraction experiments. The molecule has a tetrahedral geometry and two ligand planes are almost perpendicular to each other.

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JO - Chemistry Letters

JF - Chemistry Letters

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ER -

Single-component molecular conductor [Zn(tmdt)₂] and related Zn complexes

Abstract

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