Solubility of CaS in CaCl                         2                         LiCl eutectic melt

Takahiro Matsuzaki; Ryosuke O. Suzuki; Shungo Natsui; Tatsuya Kikuchi; Mikito Ueda

doi:10.2320/matertrans.MA201809

Solubility of CaS in CaCl ₂ LiCl eutectic melt

Takahiro Matsuzaki, Ryosuke O. Suzuki, Shungo Natsui, Tatsuya Kikuchi, Mikito Ueda

IMRAM - Division of Process and System Engineering

Hokkaido University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Solubility of CaS in molten CaCl ₂ 65 mol%LiCl eutectic salt was examined by sampling of CaS saturated salt and ICP analysis. The handling in dried environment and an adequate mass of melt were applied for reliable measurements, in addition to suppression of inclusion of CaS particles. The solubility limit was found to be 0.22 « 0.05, and 0.31 « 0.05 mol%CaS at 873 K and 973 K, respectively. This saturation value was less than 1.77 « 0.1 mol%CaS in pure CaCl ₂ at 1173 K.

Original language	English
Pages (from-to)	411-415
Number of pages	5
Journal	Materials Transactions
Volume	60
Issue number	3
DOIs	https://doi.org/10.2320/matertrans.MA201809
Publication status	Published - 2019

Keywords

CaCl LiCl eutectic salt
Calcium sulfide
Solubility

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10.2320/matertrans.MA201809

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title = " Solubility of CaS in CaCl 2 LiCl eutectic melt ",

abstract = " Solubility of CaS in molten CaCl 2 65 mol%LiCl eutectic salt was examined by sampling of CaS saturated salt and ICP analysis. The handling in dried environment and an adequate mass of melt were applied for reliable measurements, in addition to suppression of inclusion of CaS particles. The solubility limit was found to be 0.22 « 0.05, and 0.31 « 0.05 mol%CaS at 873 K and 973 K, respectively. This saturation value was less than 1.77 « 0.1 mol%CaS in pure CaCl 2 at 1173 K.",

keywords = "CaCl LiCl eutectic salt, Calcium sulfide, Solubility",

author = "Takahiro Matsuzaki and Suzuki, {Ryosuke O.} and Shungo Natsui and Tatsuya Kikuchi and Mikito Ueda",

note = "Funding Information: This work was financially supported in part by the Grant-in-Aid for Scientific Research (KAKENHI, #17H03434), and Japan Mining Industry Association (JMIA). Publisher Copyright: {\textcopyright}2019 The Japan Institute of Metals and Materials",

year = "2019",

doi = "10.2320/matertrans.MA201809",

language = "English",

volume = "60",

pages = "411--415",

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TY - JOUR

T1 - Solubility of CaS in CaCl 2 LiCl eutectic melt

AU - Matsuzaki, Takahiro

AU - Suzuki, Ryosuke O.

AU - Natsui, Shungo

AU - Kikuchi, Tatsuya

AU - Ueda, Mikito

N1 - Funding Information: This work was financially supported in part by the Grant-in-Aid for Scientific Research (KAKENHI, #17H03434), and Japan Mining Industry Association (JMIA). Publisher Copyright: ©2019 The Japan Institute of Metals and Materials

PY - 2019

Y1 - 2019

N2 - Solubility of CaS in molten CaCl 2 65 mol%LiCl eutectic salt was examined by sampling of CaS saturated salt and ICP analysis. The handling in dried environment and an adequate mass of melt were applied for reliable measurements, in addition to suppression of inclusion of CaS particles. The solubility limit was found to be 0.22 « 0.05, and 0.31 « 0.05 mol%CaS at 873 K and 973 K, respectively. This saturation value was less than 1.77 « 0.1 mol%CaS in pure CaCl 2 at 1173 K.

AB - Solubility of CaS in molten CaCl 2 65 mol%LiCl eutectic salt was examined by sampling of CaS saturated salt and ICP analysis. The handling in dried environment and an adequate mass of melt were applied for reliable measurements, in addition to suppression of inclusion of CaS particles. The solubility limit was found to be 0.22 « 0.05, and 0.31 « 0.05 mol%CaS at 873 K and 973 K, respectively. This saturation value was less than 1.77 « 0.1 mol%CaS in pure CaCl 2 at 1173 K.

KW - CaCl LiCl eutectic salt

KW - Calcium sulfide

KW - Solubility

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DO - 10.2320/matertrans.MA201809

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EP - 415

JO - Materials Transactions

JF - Materials Transactions

IS - 3

ER -

Solubility of CaS in CaCl ₂ LiCl eutectic melt

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Keywords

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