TY - GEN
T1 - Solubility of rare earth oxides in the NaCl-2CsCl melt
AU - Jiao, Shuqiang
AU - Qi, Xue
AU - Xiao, Saijun
AU - Zhu, Hongmin
AU - Sato, Yuzuru
AU - Yamamura, Tsutomu
PY - 2006
Y1 - 2006
N2 - This work presents a study on the chemical and electrochemical properties of rare earth chloride (MCl3, M = La, Ce) in the molten chloride mixture NaCl-2CsCl (mole ratio) at a temperature of 873K. The identification of the M-O (M = La, Ce) compounds that are stable in the electrolyte as well as the determination of their solubility products was carried out by Potentiometrie titration using an oxide ion sensor. The E-pO2- (potentialoxide ion) diagram for M-O compound stable has been constructed by combining both theoretical and experimental data.
AB - This work presents a study on the chemical and electrochemical properties of rare earth chloride (MCl3, M = La, Ce) in the molten chloride mixture NaCl-2CsCl (mole ratio) at a temperature of 873K. The identification of the M-O (M = La, Ce) compounds that are stable in the electrolyte as well as the determination of their solubility products was carried out by Potentiometrie titration using an oxide ion sensor. The E-pO2- (potentialoxide ion) diagram for M-O compound stable has been constructed by combining both theoretical and experimental data.
UR - http://www.scopus.com/inward/record.url?scp=40249117395&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=40249117395&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:40249117395
SN - 9781566775144
T3 - Proceedings - Electrochemical Society
SP - 713
EP - 719
BT - Molten Salts XIV - Proceedings of the International Symposium
T2 - 206th ECS Meeting
Y2 - 3 October 2004 through 8 October 2004
ER -