Solvent-mediated tuning of the regioselectivity of intramolecular diaryl ether formation: Total synthesis of (+)-aspercyclide C

Tatsuya Yoshino; Shuji Yamashita; Itaru Sato; Yujiro Hayashi; Masahiro Hirama

doi:10.1246/cl.131045

Solvent-mediated tuning of the regioselectivity of intramolecular diaryl ether formation: Total synthesis of (+)-aspercyclide C

Tatsuya Yoshino, Shuji Yamashita, Itaru Sato, Yujiro Hayashi, Masahiro Hirama

SCI - Chemistry

Tohoku University

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

A concise total synthesis of the 11-membered cyclic (+)-aspercyclide C is reported. Key to success was the fine-tuning of the reaction media to realize an oxidative, macrocyclic diaryl C-O bond formation in a regioselective and direct fashion.

Original language	English
Pages (from-to)	349-351
Number of pages	3
Journal	Chemistry Letters
Volume	43
Issue number	3
DOIs	https://doi.org/10.1246/cl.131045
Publication status	Published - 2014

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title = "Solvent-mediated tuning of the regioselectivity of intramolecular diaryl ether formation: Total synthesis of (+)-aspercyclide C",

abstract = "A concise total synthesis of the 11-membered cyclic (+)-aspercyclide C is reported. Key to success was the fine-tuning of the reaction media to realize an oxidative, macrocyclic diaryl C-O bond formation in a regioselective and direct fashion.",

author = "Tatsuya Yoshino and Shuji Yamashita and Itaru Sato and Yujiro Hayashi and Masahiro Hirama",

year = "2014",

doi = "10.1246/cl.131045",

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journal = "Chemistry Letters",

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publisher = "The Chemical Society of Japan",

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T2 - Total synthesis of (+)-aspercyclide C

AU - Yoshino, Tatsuya

AU - Yamashita, Shuji

AU - Sato, Itaru

AU - Hayashi, Yujiro

AU - Hirama, Masahiro

PY - 2014

Y1 - 2014

N2 - A concise total synthesis of the 11-membered cyclic (+)-aspercyclide C is reported. Key to success was the fine-tuning of the reaction media to realize an oxidative, macrocyclic diaryl C-O bond formation in a regioselective and direct fashion.

AB - A concise total synthesis of the 11-membered cyclic (+)-aspercyclide C is reported. Key to success was the fine-tuning of the reaction media to realize an oxidative, macrocyclic diaryl C-O bond formation in a regioselective and direct fashion.

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DO - 10.1246/cl.131045

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Solvent-mediated tuning of the regioselectivity of intramolecular diaryl ether formation: Total synthesis of (+)-aspercyclide C

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