Specific interaction between 5'-aminonucleosides and borates and influence of borates on nucleoside conformations.

T. Wada; N. Minamimoto; Y. Inaki; Y. Inoue

Specific interaction between 5'-aminonucleosides and borates and influence of borates on nucleoside conformations.

T. Wada, N. Minamimoto, Y. Inaki, Y. Inoue

IMRAM - Division of Organic- and Biomaterials Research

Osaka University

Research output: Contribution to journal › Article › peer-review

Abstract

The unique conformation and orientational change of 5'-amino-5'-deoxyuridine in Kolthoff's buffer is discussed. From CD and NOE spectra, anomalous syn orientation of Urd-5'-NH2 might be caused by specific interaction between borates and Urd-5'-NH2, which promote the formation of hydrogen bonding between 2-carbonyl oxygen and hydrogen of 5'-amino group. This borates induced syn orientation of Urd-5'-NH2 could be applied to external stimulation control of target RNA/DNA hybridization.

Original language	English
Pages (from-to)	9-10
Number of pages	2
Journal	Nucleic acids symposium series
Issue number	37
Publication status	Published - 1997

Cite this

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title = "Specific interaction between 5'-aminonucleosides and borates and influence of borates on nucleoside conformations.",

abstract = "The unique conformation and orientational change of 5'-amino-5'-deoxyuridine in Kolthoff's buffer is discussed. From CD and NOE spectra, anomalous syn orientation of Urd-5'-NH2 might be caused by specific interaction between borates and Urd-5'-NH2, which promote the formation of hydrogen bonding between 2-carbonyl oxygen and hydrogen of 5'-amino group. This borates induced syn orientation of Urd-5'-NH2 could be applied to external stimulation control of target RNA/DNA hybridization.",

author = "T. Wada and N. Minamimoto and Y. Inaki and Y. Inoue",

year = "1997",

language = "English",

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journal = "Nucleic acids symposium series",

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T1 - Specific interaction between 5'-aminonucleosides and borates and influence of borates on nucleoside conformations.

AU - Wada, T.

AU - Minamimoto, N.

AU - Inaki, Y.

AU - Inoue, Y.

PY - 1997

Y1 - 1997

N2 - The unique conformation and orientational change of 5'-amino-5'-deoxyuridine in Kolthoff's buffer is discussed. From CD and NOE spectra, anomalous syn orientation of Urd-5'-NH2 might be caused by specific interaction between borates and Urd-5'-NH2, which promote the formation of hydrogen bonding between 2-carbonyl oxygen and hydrogen of 5'-amino group. This borates induced syn orientation of Urd-5'-NH2 could be applied to external stimulation control of target RNA/DNA hybridization.

AB - The unique conformation and orientational change of 5'-amino-5'-deoxyuridine in Kolthoff's buffer is discussed. From CD and NOE spectra, anomalous syn orientation of Urd-5'-NH2 might be caused by specific interaction between borates and Urd-5'-NH2, which promote the formation of hydrogen bonding between 2-carbonyl oxygen and hydrogen of 5'-amino group. This borates induced syn orientation of Urd-5'-NH2 could be applied to external stimulation control of target RNA/DNA hybridization.

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IS - 37

ER -

Specific interaction between 5'-aminonucleosides and borates and influence of borates on nucleoside conformations.

Abstract

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