Stereoselective synthesis of a KLM ring model of ciguatoxin: Confirmation of the C54 stereochemistry

Makoto Sasaki; Atsuhiro Hasegawa; Kazuo Tachibana

doi:10.1016/S0040-4039(00)61366-7

Stereoselective synthesis of a KLM ring model of ciguatoxin: Confirmation of the C54 stereochemistry

Makoto Sasaki, Atsuhiro Hasegawa, Kazuo Tachibana

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A ciguatoxin KLM ring model and its C54 epimer were stereoselectively synthesized. Comparison of their ¹H NMR data with that on the natural toxin established the earlier stereochemical assignment at the C54 position.

Original language	English
Pages (from-to)	8489-8492
Number of pages	4
Journal	Tetrahedron Letters
Volume	34
Issue number	52
DOIs	https://doi.org/10.1016/S0040-4039(00)61366-7
Publication status	Published - 1993
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)61366-7

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title = "Stereoselective synthesis of a KLM ring model of ciguatoxin: Confirmation of the C54 stereochemistry",

abstract = "A ciguatoxin KLM ring model and its C54 epimer were stereoselectively synthesized. Comparison of their 1H NMR data with that on the natural toxin established the earlier stereochemical assignment at the C54 position.",

author = "Makoto Sasaki and Atsuhiro Hasegawa and Kazuo Tachibana",

year = "1993",

doi = "10.1016/S0040-4039(00)61366-7",

language = "English",

volume = "34",

pages = "8489--8492",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "52",

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T1 - Stereoselective synthesis of a KLM ring model of ciguatoxin

T2 - Confirmation of the C54 stereochemistry

AU - Sasaki, Makoto

AU - Hasegawa, Atsuhiro

AU - Tachibana, Kazuo

PY - 1993

Y1 - 1993

N2 - A ciguatoxin KLM ring model and its C54 epimer were stereoselectively synthesized. Comparison of their 1H NMR data with that on the natural toxin established the earlier stereochemical assignment at the C54 position.

AB - A ciguatoxin KLM ring model and its C54 epimer were stereoselectively synthesized. Comparison of their 1H NMR data with that on the natural toxin established the earlier stereochemical assignment at the C54 position.

UR - http://www.scopus.com/inward/record.url?scp=0027751677&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0027751677&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)61366-7

DO - 10.1016/S0040-4039(00)61366-7

M3 - Article

AN - SCOPUS:0027751677

SN - 0040-4039

VL - 34

SP - 8489

EP - 8492

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 52

ER -

Stereoselective synthesis of a KLM ring model of ciguatoxin: Confirmation of the C54 stereochemistry

Abstract

ASJC Scopus subject areas

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