Structural change accompanying electrochemical oxidation of [(η5-C5Me5)2Fe2S 4] to [(η5-C5Me5) 2Fe2S4](PF6)2

Hiroshi Ogino, Hiromi Tobita, Shinji Inomata, Mamoru Shimoi

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)


Electrochemical oxidation of [(η5-C5Me 5)2Fe2S4] in MeCN containing NH 4PF6 affords [(η5-C5Me 5)2Fe2S4](PF6) 2 in which a bidentate μ-S2 ligand in the parent complex is converted to a doubly bidentate μ-S2 ligand; the structure of the resulting Fe2S4 core can be described as a distorted octahedron, as shown by an X-ray crystal structure determination.

Original languageEnglish
Pages (from-to)586-587
Number of pages2
JournalChemical Communications
Issue number9
Publication statusPublished - 1988


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