Structural change accompanying electrochemical oxidation of [(η5-C5Me5)2Fe2S 4] to [(η5-C5Me5) 2Fe2S4](PF6)2

Hiroshi Ogino; Hiromi Tobita; Shinji Inomata; Mamoru Shimoi

doi:10.1039/C39880000586

Structural change accompanying electrochemical oxidation of [(η⁵-C₅Me₅)₂Fe₂S ₄] to [(η⁵-C₅Me₅) ₂Fe₂S₄](PF₆)₂

Hiroshi Ogino, Hiromi Tobita, Shinji Inomata, Mamoru Shimoi

IEHE - Institute for Excellence in Higher Education (organization affiliation only)

Tohoku University

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Electrochemical oxidation of [(η⁵-C₅Me ₅)₂Fe₂S₄] in MeCN containing NH ₄PF₆ affords [(η⁵-C₅Me ₅)₂Fe₂S₄](PF₆) ₂ in which a bidentate μ-S₂ ligand in the parent complex is converted to a doubly bidentate μ-S₂ ligand; the structure of the resulting Fe₂S₄ core can be described as a distorted octahedron, as shown by an X-ray crystal structure determination.

Original language	English
Pages (from-to)	586-587
Number of pages	2
Journal	Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/C39880000586
Publication status	Published - 1988

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title = "Structural change accompanying electrochemical oxidation of [(η5-C5Me5)2Fe2S 4] to [(η5-C5Me5) 2Fe2S4](PF6)2",

abstract = "Electrochemical oxidation of [(η5-C5Me 5)2Fe2S4] in MeCN containing NH 4PF6 affords [(η5-C5Me 5)2Fe2S4](PF6) 2 in which a bidentate μ-S2 ligand in the parent complex is converted to a doubly bidentate μ-S2 ligand; the structure of the resulting Fe2S4 core can be described as a distorted octahedron, as shown by an X-ray crystal structure determination.",

author = "Hiroshi Ogino and Hiromi Tobita and Shinji Inomata and Mamoru Shimoi",

year = "1988",

doi = "10.1039/C39880000586",

language = "English",

pages = "586--587",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Structural change accompanying electrochemical oxidation of [(η5-C5Me5)2Fe2S 4] to [(η5-C5Me5) 2Fe2S4](PF6)2

AU - Ogino, Hiroshi

AU - Tobita, Hiromi

AU - Inomata, Shinji

AU - Shimoi, Mamoru

PY - 1988

Y1 - 1988

N2 - Electrochemical oxidation of [(η5-C5Me 5)2Fe2S4] in MeCN containing NH 4PF6 affords [(η5-C5Me 5)2Fe2S4](PF6) 2 in which a bidentate μ-S2 ligand in the parent complex is converted to a doubly bidentate μ-S2 ligand; the structure of the resulting Fe2S4 core can be described as a distorted octahedron, as shown by an X-ray crystal structure determination.

AB - Electrochemical oxidation of [(η5-C5Me 5)2Fe2S4] in MeCN containing NH 4PF6 affords [(η5-C5Me 5)2Fe2S4](PF6) 2 in which a bidentate μ-S2 ligand in the parent complex is converted to a doubly bidentate μ-S2 ligand; the structure of the resulting Fe2S4 core can be described as a distorted octahedron, as shown by an X-ray crystal structure determination.

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JO - Chemical Communications

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IS - 9

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Structural change accompanying electrochemical oxidation of [(η⁵-C₅Me₅)₂Fe₂S ₄] to [(η⁵-C₅Me₅) ₂Fe₂S₄](PF₆)₂

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