Structure of gel-derived and quenched glasses in the Al2O 3-ZrO2-SiO2 system

M. Popa, J. Frantti, M. Kakihana

    Research output: Contribution to journalConference articlepeer-review

    1 Citation (Scopus)

    Abstract

    Amorphous materials in the system Al]2O3-ZrO 2-SiO2 are of interest in various areas of materials science, such as alkali resistant glasses, chemically stable refractories, glass ceramics or zirconia toughened ceramics. In the present research the glass formation in the SiO2-rich region of the ternary oxide system Al 2O3-ZrO2-SiO2 is analyzed. Gels have been synthesized by the sol-gel method in acid media and then treated up to 1650°C. The presence of Zr and Al ions into the silica network are investigated by means of UV-Raman spectroscopy. The crystallization of gels and the crystalline phases formed at different thermal treatment temperatures as well as phases evolution with the temperature were studied.

    Original languageEnglish
    Pages (from-to)1851-1854
    Number of pages4
    JournalKey Engineering Materials
    Volume264-268
    Issue numberIII
    Publication statusPublished - 2004 Jan 1
    EventProceedings of the 8th Conference and Exhibition of the European Ceramic Society - Istanbul, Turkey
    Duration: 2003 Jun 292003 Jul 3

    Keywords

    • AlO-ZrO-SiO ternary system
    • Sol-gel method
    • UV Raman spectroscopy

    ASJC Scopus subject areas

    • Materials Science(all)
    • Mechanics of Materials
    • Mechanical Engineering

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