TY - JOUR
T1 - Studies on catalysis by molten metals. X. Hydrogen transfer reactions between alcohols and ketones on liquid indium catalyst
AU - Miyamoto, Akira
AU - Ogino, Yoshisada
N1 - Copyright:
Copyright 2014 Elsevier B.V., All rights reserved.
PY - 1976/6/30
Y1 - 1976/6/30
N2 - Hydrogen transfer reactions between alcohols and ketones were studied on liquid indium catalyst by using a pulse reaction technique, and a plausible reaction model is proposed to explain the experimental results including deuterium isotope effects. Further, the stereoselectivity observed in the transfer hydrogenation of methylcyclohexanones and the selectivities observed in the transfer hydrogenation of unsaturated ketones are discussed in terms of the proposed model.
AB - Hydrogen transfer reactions between alcohols and ketones were studied on liquid indium catalyst by using a pulse reaction technique, and a plausible reaction model is proposed to explain the experimental results including deuterium isotope effects. Further, the stereoselectivity observed in the transfer hydrogenation of methylcyclohexanones and the selectivities observed in the transfer hydrogenation of unsaturated ketones are discussed in terms of the proposed model.
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U2 - 10.1016/0021-9517(76)90301-8
DO - 10.1016/0021-9517(76)90301-8
M3 - Article
AN - SCOPUS:49549128834
SN - 0021-9517
VL - 43
SP - 143
EP - 153
JO - Journal of Catalysis
JF - Journal of Catalysis
IS - 1-3
ER -