Sulfonyl-containing polymer and its alumina nanocomposite with high Abbe number and high refractive index

Bin Cai, Toshikuni Kaino, Okihiro Sugihara

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

In this study, we focus on refractive-index and Abbe-number improvements to optical polyesters. First, we modify polymers by introducing sulfonyl groups and removing phenyl groups in the monomer structure. In this manner, new polymers with Abbe numbers higher than 40 are synthesized. To further increase the refractive index and Abbe number, the polymers are hybridized with well-dispersed alumina nanoparticles (NPs). The prepared polymer/alumina nanocomposites have a high refractive index and Abbe number; (nD = 1.580 and VD = 55) and (nD = 1.631 and VD = 53), which easily exceeds the empirical "limiting line" of conventional optical polymers.

Original languageEnglish
Pages (from-to)1210-1216
Number of pages7
JournalOptical Materials Express
Volume5
Issue number5
DOIs
Publication statusPublished - 2015

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

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