- salt with flexible supramolecular cation rotator

Qiong Ye, Ping Ping Shi, Zi Qi Chen, Tomoyuki Akutagawa, Shin Ichiro Noro, Takayoshi Nakamura

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

[Ni(dmit) 2] - salt (dmit 2 - 2-thioxo-1,3-dithiole-4,5-dithiolate) with flexible supramolecular cation (4-cyanomethylanilinium)(dibenzo[18]crown-6) has been synthesized and investigated its structure, magnetism and rotation. The comparable large steric hindrances limit the rotation of cyanomethyl group to result in no phase transition occurred. Magnetic and potential energy calculations by DFT method were consistent with the magnetic and structure measurements.

Original languageEnglish
Pages (from-to)219-224
Number of pages6
JournalInorganic Chemistry Communication
Volume20
DOIs
Publication statusPublished - 2012 Jun

Keywords

  • Crystal engineering
  • Flexible
  • Molecular rotator
  • Supramolecule

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