2D- and 1H-NMR in α-(h8-ET)2ND4Hg(SCN)4 and α-(d8-ET)2NH4Hg(SCN)4

S. Endo; T. Goto; T. Fukase; H. Uozaki; K. Okamoto; M. Yamaguchi; N. Toyota

doi:10.1016/S0379-6779(98)00425-1

²D- and ¹H-NMR in α-(h₈-ET)₂ND₄Hg(SCN)₄ and α-(d₈-ET)₂NH₄Hg(SCN)₄

S. Endo, T. Goto, T. Fukase, H. Uozaki, K. Okamoto, M. Yamaguchi, N. Toyota

Research output: Contribution to journal › Conference article › peer-review

Abstract

We have measured the temperature dependence of the spectrum and the spin-lattice relaxation time T₁ by ²D nuclear-magnetic-resonance (NMR) for α-(h₈-ET)₂ND₄Hg(SCN)₄ and ¹H-NMR for α-(d₈-ET)₂NH₄Hg(SCN)₄ in order to clarify the molecular dynamics of the non-centrosymmetric ND₄⁺ and NH₄⁺ ions. Both the systems show the peak in T₁^-1 around 40 K explained by Bloembergen-Purcell-Pound model, while the temperature dependence of the spectra were quite different.

Original language	English
Pages (from-to)	2073-2074
Number of pages	2
Journal	Synthetic Metals
Volume	103
Issue number	1-3
DOIs	https://doi.org/10.1016/S0379-6779(98)00425-1
Publication status	Published - 1999 Jun 24
Externally published	Yes
Event	Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) - Montpellier Duration: 1998 Jul 12 → 1998 Jul 18

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/S0379-6779(98)00425-1

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title = "2D- and 1H-NMR in α-(h8-ET)2ND4Hg(SCN)4 and α-(d8-ET)2NH4Hg(SCN)4",

abstract = "We have measured the temperature dependence of the spectrum and the spin-lattice relaxation time T1 by 2D nuclear-magnetic-resonance (NMR) for α-(h8-ET)2ND4Hg(SCN)4 and 1H-NMR for α-(d8-ET)2NH4Hg(SCN)4 in order to clarify the molecular dynamics of the non-centrosymmetric ND4+ and NH4+ ions. Both the systems show the peak in T1-1 around 40 K explained by Bloembergen-Purcell-Pound model, while the temperature dependence of the spectra were quite different.",

author = "S. Endo and T. Goto and T. Fukase and H. Uozaki and K. Okamoto and M. Yamaguchi and N. Toyota",

year = "1999",

month = jun,

day = "24",

doi = "10.1016/S0379-6779(98)00425-1",

language = "English",

volume = "103",

pages = "2073--2074",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier BV",

number = "1-3",

note = "Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) ; Conference date: 12-07-1998 Through 18-07-1998",

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TY - JOUR

T1 - 2D- and 1H-NMR in α-(h8-ET)2ND4Hg(SCN)4 and α-(d8-ET)2NH4Hg(SCN)4

AU - Endo, S.

AU - Goto, T.

AU - Fukase, T.

AU - Uozaki, H.

AU - Okamoto, K.

AU - Yamaguchi, M.

AU - Toyota, N.

PY - 1999/6/24

Y1 - 1999/6/24

N2 - We have measured the temperature dependence of the spectrum and the spin-lattice relaxation time T1 by 2D nuclear-magnetic-resonance (NMR) for α-(h8-ET)2ND4Hg(SCN)4 and 1H-NMR for α-(d8-ET)2NH4Hg(SCN)4 in order to clarify the molecular dynamics of the non-centrosymmetric ND4+ and NH4+ ions. Both the systems show the peak in T1-1 around 40 K explained by Bloembergen-Purcell-Pound model, while the temperature dependence of the spectra were quite different.

AB - We have measured the temperature dependence of the spectrum and the spin-lattice relaxation time T1 by 2D nuclear-magnetic-resonance (NMR) for α-(h8-ET)2ND4Hg(SCN)4 and 1H-NMR for α-(d8-ET)2NH4Hg(SCN)4 in order to clarify the molecular dynamics of the non-centrosymmetric ND4+ and NH4+ ions. Both the systems show the peak in T1-1 around 40 K explained by Bloembergen-Purcell-Pound model, while the temperature dependence of the spectra were quite different.

UR - http://www.scopus.com/inward/record.url?scp=0033138189&partnerID=8YFLogxK

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U2 - 10.1016/S0379-6779(98)00425-1

DO - 10.1016/S0379-6779(98)00425-1

M3 - Conference article

AN - SCOPUS:0033138189

SN - 0379-6779

VL - 103

SP - 2073

EP - 2074

JO - Synthetic Metals

JF - Synthetic Metals

IS - 1-3

T2 - Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98)

Y2 - 12 July 1998 through 18 July 1998

ER -

²D- and ¹H-NMR in α-(h₈-ET)₂ND₄Hg(SCN)₄ and α-(d₈-ET)₂NH₄Hg(SCN)₄

Abstract

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