Superelectrons from Shrunken Atoms in the Charge-Transfer Organic Compounds

M. Fukuhara

doi:10.1080/10587259508034570

Superelectrons from Shrunken Atoms in the Charge-Transfer Organic Compounds

M. Fukuhara

New Industry Creation Hatchery Center (NICHe)

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The atomic distance between shrunken atoms in five representative organic charge-transfer superconductors, (TMTSF)₂C10₄ β-(BEDT-TTF)₂I₃, β-(BEDT-TTF)₂IBr₂, κ-(bedt-ttf)2 cu[n(cn)₂](NCS)₂ and K₃C₆₀ were calculated and the shrunken atoms were related to T_c in comparison with inorganic superconductors. The main role of charge transfer force between the cation stack and the insulating layers of anion in the organic superconductors is a compression of the spherical inner paired electron clouds toward to the nucleus, the so-called pintch effect. T_c increases as the pintch effect increases. The electron pair set, 3d¹⁰and 2p⁶, derived from the compressed atoms, Se and S, respectively, in organic superconductors can be explained as an origin of superelectrons, as well as superconducting inorganic compounds and elements.

Original language	English
Pages (from-to)	299-314
Number of pages	16
Journal	Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
Volume	258
Issue number	1
DOIs	https://doi.org/10.1080/10587259508034570
Publication status	Published - 1995 Jan 1

Keywords

Superelectron
electron pair set
pintch effect
shrunken atom

ASJC Scopus subject areas

Condensed Matter Physics

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10.1080/10587259508034570

Cite this

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abstract = "The atomic distance between shrunken atoms in five representative organic charge-transfer superconductors, (TMTSF)2C104 β-(BEDT-TTF)2I3, β-(BEDT-TTF)2IBr2, κ-(bedt-ttf)2 cu[n(cn)2](NCS)2 and K3C60 were calculated and the shrunken atoms were related to Tc in comparison with inorganic superconductors. The main role of charge transfer force between the cation stack and the insulating layers of anion in the organic superconductors is a compression of the spherical inner paired electron clouds toward to the nucleus, the so-called pintch effect. Tc increases as the pintch effect increases. The electron pair set, 3d10and 2p6, derived from the compressed atoms, Se and S, respectively, in organic superconductors can be explained as an origin of superelectrons, as well as superconducting inorganic compounds and elements.",

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AB - The atomic distance between shrunken atoms in five representative organic charge-transfer superconductors, (TMTSF)2C104 β-(BEDT-TTF)2I3, β-(BEDT-TTF)2IBr2, κ-(bedt-ttf)2 cu[n(cn)2](NCS)2 and K3C60 were calculated and the shrunken atoms were related to Tc in comparison with inorganic superconductors. The main role of charge transfer force between the cation stack and the insulating layers of anion in the organic superconductors is a compression of the spherical inner paired electron clouds toward to the nucleus, the so-called pintch effect. Tc increases as the pintch effect increases. The electron pair set, 3d10and 2p6, derived from the compressed atoms, Se and S, respectively, in organic superconductors can be explained as an origin of superelectrons, as well as superconducting inorganic compounds and elements.

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Superelectrons from Shrunken Atoms in the Charge-Transfer Organic Compounds

Abstract

Keywords

ASJC Scopus subject areas

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