Supramolecular architectonics with carbon nanoclusters

Jian Yu Zheng; Kentaro Tashiro; Yusuke Hirabayashi; Kazushi Kinbara; Kazuhiko Saigo; Takuzo Aida; Shigeru Sakamoto; Kentaro Yamaguchi

doi:10.1002/1521-3773(20010518)40:10<1857::AID-ANIE1857>3.0.CO;2-Y

Supramolecular architectonics with carbon nanoclusters

Jian Yu Zheng, Kentaro Tashiro, Yusuke Hirabayashi, Kazushi Kinbara, Kazuhiko Saigo, Takuzo Aida, Shigeru Sakamoto, Kentaro Yamaguchi

Institute of Multidisciplinary Research for Advanced Materials (IMRAM)

Research output: Contribution to journal › Article › peer-review

157 Citations (Scopus)

Abstract

Supramolecular interaction of fullerenes with cyclic dimers metalloporphyrins (1-m, M = central metal ions) showed a pronounced dependence on the nature of the metal ions, whereby 1-RhMe/fullerene systems displayed extremely high association constants (ca. 10⁸M^-1) and low dissociaton activities. Crystal-structure analysis and NMR data suggested a charge-transfer interaction and van der Waals interactions between the host and guest.

Original language	English
Pages (from-to)	1857-1861
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	10
DOIs	https://doi.org/10.1002/1521-3773(20010518)40:10<1857::AID-ANIE1857>3.0.CO;2-Y
Publication status	Published - 2001 May 18

Keywords

Fullerenes
Inclusion compunds
Pi interactions
Porphyrinoids
Rhodium

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/1521-3773(20010518)40:10<1857::AID-ANIE1857>3.0.CO;2-Y

Cite this

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title = "Supramolecular architectonics with carbon nanoclusters",

abstract = "Supramolecular interaction of fullerenes with cyclic dimers metalloporphyrins (1-m, M = central metal ions) showed a pronounced dependence on the nature of the metal ions, whereby 1-RhMe/fullerene systems displayed extremely high association constants (ca. 108M-1) and low dissociaton activities. Crystal-structure analysis and NMR data suggested a charge-transfer interaction and van der Waals interactions between the host and guest.",

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T1 - Supramolecular architectonics with carbon nanoclusters

AU - Zheng, Jian Yu

AU - Tashiro, Kentaro

AU - Hirabayashi, Yusuke

AU - Kinbara, Kazushi

AU - Saigo, Kazuhiko

AU - Aida, Takuzo

AU - Sakamoto, Shigeru

AU - Yamaguchi, Kentaro

PY - 2001/5/18

Y1 - 2001/5/18

N2 - Supramolecular interaction of fullerenes with cyclic dimers metalloporphyrins (1-m, M = central metal ions) showed a pronounced dependence on the nature of the metal ions, whereby 1-RhMe/fullerene systems displayed extremely high association constants (ca. 108M-1) and low dissociaton activities. Crystal-structure analysis and NMR data suggested a charge-transfer interaction and van der Waals interactions between the host and guest.

AB - Supramolecular interaction of fullerenes with cyclic dimers metalloporphyrins (1-m, M = central metal ions) showed a pronounced dependence on the nature of the metal ions, whereby 1-RhMe/fullerene systems displayed extremely high association constants (ca. 108M-1) and low dissociaton activities. Crystal-structure analysis and NMR data suggested a charge-transfer interaction and van der Waals interactions between the host and guest.

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KW - Inclusion compunds

KW - Pi interactions

KW - Porphyrinoids

KW - Rhodium

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Supramolecular architectonics with carbon nanoclusters

Abstract

Keywords

ASJC Scopus subject areas

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