Supramolecular assembly based on π-π stacking and π-cation interactions between thiacalix[6]arene and DMF

Fumio Hamada; Yutaka Higuchi; Yoshihiko Kondo; Chizuko Kabuto; Nobuhiko Iki

doi:10.1016/j.tetlet.2006.05.055

Supramolecular assembly based on π-π stacking and π-cation interactions between thiacalix[6]arene and DMF

Fumio Hamada, Yutaka Higuchi, Yoshihiko Kondo, Chizuko Kabuto, Nobuhiko Iki

ENV - Frontier Science for Advanced Environment

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The molecular assembly of thiacalix[6]arene was formed by π-π stacking and π-DMF interactions between thiacalix[6]arene and adjoining thiacalix[6]arene and between thiacalix[6]arene and DMF, respectively. The X-ray crystal analysis also revealed that hydroxyl groups of thiacalix[6]arene adopted novel two sets of hydrogen bond with two DMF and intramolecular hydrogen bond between phenolic units, which cause to make 1,2,3-alternate configuration structure of thiacalix[6]arene.

Original language	English
Pages (from-to)	5591-5593
Number of pages	3
Journal	Tetrahedron Letters
Volume	47
Issue number	31
DOIs	https://doi.org/10.1016/j.tetlet.2006.05.055
Publication status	Published - 2006 Jul 31

Keywords

π-π Stacking interaction
π-DMF interaction
Crystal structure
Hydrogen bond
Thiacalixarenes

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10.1016/j.tetlet.2006.05.055

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title = "Supramolecular assembly based on π-π stacking and π-cation interactions between thiacalix[6]arene and DMF",

abstract = "The molecular assembly of thiacalix[6]arene was formed by π-π stacking and π-DMF interactions between thiacalix[6]arene and adjoining thiacalix[6]arene and between thiacalix[6]arene and DMF, respectively. The X-ray crystal analysis also revealed that hydroxyl groups of thiacalix[6]arene adopted novel two sets of hydrogen bond with two DMF and intramolecular hydrogen bond between phenolic units, which cause to make 1,2,3-alternate configuration structure of thiacalix[6]arene.",

keywords = "π-π Stacking interaction, π-DMF interaction, Crystal structure, Hydrogen bond, Thiacalixarenes",

author = "Fumio Hamada and Yutaka Higuchi and Yoshihiko Kondo and Chizuko Kabuto and Nobuhiko Iki",

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T1 - Supramolecular assembly based on π-π stacking and π-cation interactions between thiacalix[6]arene and DMF

AU - Hamada, Fumio

AU - Higuchi, Yutaka

AU - Kondo, Yoshihiko

AU - Kabuto, Chizuko

AU - Iki, Nobuhiko

PY - 2006/7/31

Y1 - 2006/7/31

N2 - The molecular assembly of thiacalix[6]arene was formed by π-π stacking and π-DMF interactions between thiacalix[6]arene and adjoining thiacalix[6]arene and between thiacalix[6]arene and DMF, respectively. The X-ray crystal analysis also revealed that hydroxyl groups of thiacalix[6]arene adopted novel two sets of hydrogen bond with two DMF and intramolecular hydrogen bond between phenolic units, which cause to make 1,2,3-alternate configuration structure of thiacalix[6]arene.

AB - The molecular assembly of thiacalix[6]arene was formed by π-π stacking and π-DMF interactions between thiacalix[6]arene and adjoining thiacalix[6]arene and between thiacalix[6]arene and DMF, respectively. The X-ray crystal analysis also revealed that hydroxyl groups of thiacalix[6]arene adopted novel two sets of hydrogen bond with two DMF and intramolecular hydrogen bond between phenolic units, which cause to make 1,2,3-alternate configuration structure of thiacalix[6]arene.

KW - π-π Stacking interaction

KW - π-DMF interaction

KW - Crystal structure

KW - Hydrogen bond

KW - Thiacalixarenes

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DO - 10.1016/j.tetlet.2006.05.055

M3 - Article

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JO - Tetrahedron Letters

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Supramolecular assembly based on π-π stacking and π-cation interactions between thiacalix[6]arene and DMF

Abstract

Keywords

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