Supramolecular porphyrin-fullerene via 'two-point' binding strategy: Axial-coordination and cation-crown ether complexation

Francis D'Souza; Raghu Chitta; Suresh Gadde; Melvin E. Zandler; Atula S.D. Sandanayaka; Yasuyuki Araki; Osamu Ito

doi:10.1039/b416736h

Supramolecular porphyrin-fullerene via 'two-point' binding strategy: Axial-coordination and cation-crown ether complexation

Francis D'Souza, Raghu Chitta, Suresh Gadde, Melvin E. Zandler, Atula S.D. Sandanayaka, Yasuyuki Araki, Osamu Ito

Division of Organic- and Biomaterials Research

Research output: Contribution to journal › Article › peer-review

93 Citations (Scopus)

Abstract

A highly stable porphyrin-fullerene conjugate with defined distance and orientation, was formed using a newly developed 'two-point' binding strategy involving axial-coordination and cation-crown ether complexation; photochemical studies performed in benzonitrile revealed efficient charge separation and slow charge-recombination in the supramolecular complex.

Original language	English
Pages (from-to)	1279-1281
Number of pages	3
Journal	Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/b416736h
Publication status	Published - 2005 Mar 14

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/b416736h

Cite this

@article{b344a4a90dbe4163bc3292ebe781ddfd,

title = "Supramolecular porphyrin-fullerene via 'two-point' binding strategy: Axial-coordination and cation-crown ether complexation",

abstract = "A highly stable porphyrin-fullerene conjugate with defined distance and orientation, was formed using a newly developed 'two-point' binding strategy involving axial-coordination and cation-crown ether complexation; photochemical studies performed in benzonitrile revealed efficient charge separation and slow charge-recombination in the supramolecular complex.",

author = "Francis D'Souza and Raghu Chitta and Suresh Gadde and Zandler, {Melvin E.} and Sandanayaka, {Atula S.D.} and Yasuyuki Araki and Osamu Ito",

year = "2005",

month = mar,

day = "14",

doi = "10.1039/b416736h",

language = "English",

pages = "1279--1281",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "10",

}

TY - JOUR

T1 - Supramolecular porphyrin-fullerene via 'two-point' binding strategy

T2 - Axial-coordination and cation-crown ether complexation

AU - D'Souza, Francis

AU - Chitta, Raghu

AU - Gadde, Suresh

AU - Zandler, Melvin E.

AU - Sandanayaka, Atula S.D.

AU - Araki, Yasuyuki

AU - Ito, Osamu

PY - 2005/3/14

Y1 - 2005/3/14

N2 - A highly stable porphyrin-fullerene conjugate with defined distance and orientation, was formed using a newly developed 'two-point' binding strategy involving axial-coordination and cation-crown ether complexation; photochemical studies performed in benzonitrile revealed efficient charge separation and slow charge-recombination in the supramolecular complex.

AB - A highly stable porphyrin-fullerene conjugate with defined distance and orientation, was formed using a newly developed 'two-point' binding strategy involving axial-coordination and cation-crown ether complexation; photochemical studies performed in benzonitrile revealed efficient charge separation and slow charge-recombination in the supramolecular complex.

UR - http://www.scopus.com/inward/record.url?scp=16244390275&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=16244390275&partnerID=8YFLogxK

U2 - 10.1039/b416736h

DO - 10.1039/b416736h

M3 - Article

C2 - 15742051

AN - SCOPUS:16244390275

SN - 1359-7345

SP - 1279

EP - 1281

JO - Chemical Communications

JF - Chemical Communications

IS - 10

ER -

Supramolecular porphyrin-fullerene via 'two-point' binding strategy: Axial-coordination and cation-crown ether complexation

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this