Supramolecular rotor: Adamantylammonium([18]crown-6) in [Ni(dmit) 2]- salt

Daisuke Sato, Tomoyuki Akutagawa, Sadamu Takeda, Shin Ichiro Noro, Takayoshi Nakamura

Research output: Contribution to journalArticlepeer-review

45 Citations (Scopus)


Adamantylammonium (ADNH3+) was complexed with [18]crown-6, forming a supramolecular cation of (ADNH3 +)([18]crown6), which was introduced into a [Ni(dmit) 2]- salt as a supramolecular rotor. The cation layers were alternately arranged with [Ni(dmit)2]- layers in the crystal, in which the molecular rotation of (ADNH3 +)([18]-crown-6) was confirmed from the temperature-dependent solid-state 1H NMR.

Original languageEnglish
Pages (from-to)363-365
Number of pages3
JournalInorganic Chemistry
Issue number2
Publication statusPublished - 2007 Jan 22


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