TY - JOUR
T1 - Syntheses and Properties of [Cu{B2H4•2P(CH3)3}2]X (X = Cl, I) and X-ray Crystal Structure of the Iodide
AU - Shimoi, Mamoru
AU - Katoh, Kinji
AU - Tobita, Hiromi
AU - Ogino, Hiroshi
PY - 1990
Y1 - 1990
N2 - Chloride and iodide salts of bis{bis(trimethylphosphine)tetrahydrodiboron-H1,H2}copper(I), [Cu{B2H4•2P(CH3)3}2]X (X = Cl, I), were prepared by the reactions of B2H4•2P(CH3)3 with the copper(I) halides. X-ray crystal structure analysis of the iodide shows that each ligand is coordinated to the copper atom through two vicinal hydrogen atoms and the copper atom is ligated with four hydrogen atoms tetrahedrally. Crystal data: monoclinic with the space group I2/a, a = 13.003 (1) Å, b = 16.257 (2) Å, c = 12.974 (3) Å,β = 92.63 (1)°, V = 2739.7 (8) Å3, Z = 4, and R(F0) = 0.057 for 1676 reflections with |f0| > 3σ(F0).
AB - Chloride and iodide salts of bis{bis(trimethylphosphine)tetrahydrodiboron-H1,H2}copper(I), [Cu{B2H4•2P(CH3)3}2]X (X = Cl, I), were prepared by the reactions of B2H4•2P(CH3)3 with the copper(I) halides. X-ray crystal structure analysis of the iodide shows that each ligand is coordinated to the copper atom through two vicinal hydrogen atoms and the copper atom is ligated with four hydrogen atoms tetrahedrally. Crystal data: monoclinic with the space group I2/a, a = 13.003 (1) Å, b = 16.257 (2) Å, c = 12.974 (3) Å,β = 92.63 (1)°, V = 2739.7 (8) Å3, Z = 4, and R(F0) = 0.057 for 1676 reflections with |f0| > 3σ(F0).
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U2 - 10.1021/ic00329a048
DO - 10.1021/ic00329a048
M3 - Article
AN - SCOPUS:4244001990
SN - 0020-1669
VL - 29
SP - 814
EP - 817
JO - Inorganic Chemistry
JF - Inorganic Chemistry
IS - 4
ER -