Synthesis and behavior in solution of the triple cubane- and windmill-type framework isomers of an organorhodium tungsten oxide cluster [(Cp*Rh)4W4O16]

Koji Nishikawa; Koichi Kido; Jun'ichi Yoshida; Takanori Nishioka; Isamu Kinoshita; Brian K. Breedlove; Yoshihito Hayashi; Akira Uehara; Kiyoshi Isobe

doi:10.1002/aoc.447

Synthesis and behavior in solution of the triple cubane- and windmill-type framework isomers of an organorhodium tungsten oxide cluster [(Cp*Rh)₄W₄O₁₆]

Koji Nishikawa, Koichi Kido, Jun'ichi Yoshida, Takanori Nishioka, Isamu Kinoshita, Brian K. Breedlove, Yoshihito Hayashi, Akira Uehara, Kiyoshi Isobe

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Two geometrical isomers of a [(Cp*Rh)₄W₄O₁₆] oxide cluster, a triple cubane-type and a windmill-type, are isolated selectively from the systems of [Cp*Rh]²⁺ and [WO₄]^2- in CH₃CN using different reaction temperatures. Both isomers, which interconvert in certain solutions, are characterized by X-ray diffraction.

Original language	English
Pages (from-to)	446-448
Number of pages	3
Journal	Applied Organometallic Chemistry
Volume	17
Issue number	6-7
DOIs	https://doi.org/10.1002/aoc.447
Publication status	Published - 2003
Externally published	Yes

Keywords

Cubic framework
Geometrical isomers
Isomerization
Organometallic oxide
Triple cubane-type
Tungsten oxide cluster
Windmill-type

ASJC Scopus subject areas

Chemistry(all)
Inorganic Chemistry

Access to Document

10.1002/aoc.447

Cite this

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title = "Synthesis and behavior in solution of the triple cubane- and windmill-type framework isomers of an organorhodium tungsten oxide cluster [(Cp*Rh)4W4O16]",

abstract = "Two geometrical isomers of a [(Cp*Rh)4W4O16] oxide cluster, a triple cubane-type and a windmill-type, are isolated selectively from the systems of [Cp*Rh]2+ and [WO4]2- in CH3CN using different reaction temperatures. Both isomers, which interconvert in certain solutions, are characterized by X-ray diffraction.",

keywords = "Cubic framework, Geometrical isomers, Isomerization, Organometallic oxide, Triple cubane-type, Tungsten oxide cluster, Windmill-type",

author = "Koji Nishikawa and Koichi Kido and Jun'ichi Yoshida and Takanori Nishioka and Isamu Kinoshita and Breedlove, {Brian K.} and Yoshihito Hayashi and Akira Uehara and Kiyoshi Isobe",

year = "2003",

doi = "10.1002/aoc.447",

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pages = "446--448",

journal = "Applied Organometallic Chemistry",

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T1 - Synthesis and behavior in solution of the triple cubane- and windmill-type framework isomers of an organorhodium tungsten oxide cluster [(Cp*Rh)4W4O16]

AU - Nishikawa, Koji

AU - Kido, Koichi

AU - Yoshida, Jun'ichi

AU - Nishioka, Takanori

AU - Kinoshita, Isamu

AU - Breedlove, Brian K.

AU - Hayashi, Yoshihito

AU - Uehara, Akira

AU - Isobe, Kiyoshi

PY - 2003

Y1 - 2003

N2 - Two geometrical isomers of a [(Cp*Rh)4W4O16] oxide cluster, a triple cubane-type and a windmill-type, are isolated selectively from the systems of [Cp*Rh]2+ and [WO4]2- in CH3CN using different reaction temperatures. Both isomers, which interconvert in certain solutions, are characterized by X-ray diffraction.

AB - Two geometrical isomers of a [(Cp*Rh)4W4O16] oxide cluster, a triple cubane-type and a windmill-type, are isolated selectively from the systems of [Cp*Rh]2+ and [WO4]2- in CH3CN using different reaction temperatures. Both isomers, which interconvert in certain solutions, are characterized by X-ray diffraction.

KW - Cubic framework

KW - Geometrical isomers

KW - Isomerization

KW - Organometallic oxide

KW - Triple cubane-type

KW - Tungsten oxide cluster

KW - Windmill-type

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