Synthesis and confirmation of the structures of polonicumtoxins A, B and C

Mari Yotsu-Yamashita; Takeshi Yasumoto; Viresh H. Rawal

doi:10.3987/com-97-8006

Synthesis and confirmation of the structures of polonicumtoxins A, B and C

Mari Yotsu-Yamashita, Takeshi Yasumoto, Viresh H. Rawal

AGR - Agricultural Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Total syntheses of polonicumtoxins A (1), B (2), and C (3) have been completed. The key step of the syntheses involves an aza-Wittig reaction for the construction of the cyclic ketimine. The synthetic compounds were found to be identical in all respects with the natural products, thus confirming their assigned structures.

Original language	English
Pages (from-to)	79-93
Number of pages	15
Journal	Heterocycles
Volume	48
Issue number	1
DOIs	https://doi.org/10.3987/com-97-8006
Publication status	Published - 1998

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

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Cite this

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abstract = "Total syntheses of polonicumtoxins A (1), B (2), and C (3) have been completed. The key step of the syntheses involves an aza-Wittig reaction for the construction of the cyclic ketimine. The synthetic compounds were found to be identical in all respects with the natural products, thus confirming their assigned structures.",

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AU - Yasumoto, Takeshi

AU - Rawal, Viresh H.

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AB - Total syntheses of polonicumtoxins A (1), B (2), and C (3) have been completed. The key step of the syntheses involves an aza-Wittig reaction for the construction of the cyclic ketimine. The synthetic compounds were found to be identical in all respects with the natural products, thus confirming their assigned structures.

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Synthesis and confirmation of the structures of polonicumtoxins A, B and C

Abstract

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