Synthesis and crystal structure analysis of Li2NaBP2O8and LiNa2B5P2O14

Toru Hasegawa; Hisanori Yamane

doi:10.1016/j.jssc.2014.11.024

Synthesis and crystal structure analysis of Li₂NaBP₂O₈and LiNa₂B₅P₂O₁₄

Toru Hasegawa, Hisanori Yamane

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Single crystals of Li₂NaBP₂O₈ and LiNa₂B₅P₂O₁₄ were prepared at 873-883 K. The XRD reflections of Li₂NaBP₂O₈ single crystal were indexed with triclinic unit-cell parameters of a = 5.4344(3) A˚, b = 7.3793 (4) A˚, c = 7.9840(4) A˚, α = 103.243(3)°, β = 109.270(4)° and γ = 87.391(2)°; (space group P1 (No. 2)). Li₂NaBP₂O₈ consists of one-dimensional _∞¹[BP₂O₈]^3- chains of BO₄ and PO₄ tetrahedra in the direction of the c axis, and Li and Na atoms located around the chains. The XRD reflections of the LiNa₂B₅P₂O₁₄ single crystal were indexed with monoclinic unit-cell parameters of a = 8.208(3) A˚, b = 9.151(3) A˚, c = 8.349(3) A˚ and β = 115.709(7)°; (space group P2₁/m (No. 11)). In the crystal structure of LiNa₂B₅P₂O₁₄, BO₃ trigonal planer and BO₄ and PO₄ tetrahedra share O atoms and form two-dimensional sheets of _∞²[B₅P₂O₁₄]^3-. One Li and two Na atoms are situated at a large triangular space in the sheets.

Original language	English
Pages (from-to)	65-71
Number of pages	7
Journal	Journal of Solid State Chemistry
Volume	225
DOIs	https://doi.org/10.1016/j.jssc.2014.11.024
Publication status	Published - 2015 May

Keywords

Borophosphate
Crystal structure
Solid-state reaction

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.jssc.2014.11.024

Cite this

@article{b4647638b3ad4106bc21bd74d8a6cad3,

title = "Synthesis and crystal structure analysis of Li2NaBP2O8and LiNa2B5P2O14",

abstract = "Single crystals of Li2NaBP2O8 and LiNa2B5P2O14 were prepared at 873-883 K. The XRD reflections of Li2NaBP2O8 single crystal were indexed with triclinic unit-cell parameters of a = 5.4344(3) A˚, b = 7.3793 (4) A˚, c = 7.9840(4) A˚, α = 103.243(3)°, β = 109.270(4)° and γ = 87.391(2)°; (space group P1 (No. 2)). Li2NaBP2O8 consists of one-dimensional ∞1[BP2O8]3- chains of BO4 and PO4 tetrahedra in the direction of the c axis, and Li and Na atoms located around the chains. The XRD reflections of the LiNa2B5P2O14 single crystal were indexed with monoclinic unit-cell parameters of a = 8.208(3) A˚, b = 9.151(3) A˚, c = 8.349(3) A˚ and β = 115.709(7)°; (space group P21/m (No. 11)). In the crystal structure of LiNa2B5P2O14, BO3 trigonal planer and BO4 and PO4 tetrahedra share O atoms and form two-dimensional sheets of ∞2[B5P2O14]3-. One Li and two Na atoms are situated at a large triangular space in the sheets.",

keywords = "Borophosphate, Crystal structure, Solid-state reaction",

author = "Toru Hasegawa and Hisanori Yamane",

year = "2015",

month = may,

doi = "10.1016/j.jssc.2014.11.024",

language = "English",

volume = "225",

pages = "65--71",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

}

TY - JOUR

T1 - Synthesis and crystal structure analysis of Li2NaBP2O8and LiNa2B5P2O14

AU - Hasegawa, Toru

AU - Yamane, Hisanori

PY - 2015/5

Y1 - 2015/5

N2 - Single crystals of Li2NaBP2O8 and LiNa2B5P2O14 were prepared at 873-883 K. The XRD reflections of Li2NaBP2O8 single crystal were indexed with triclinic unit-cell parameters of a = 5.4344(3) A˚, b = 7.3793 (4) A˚, c = 7.9840(4) A˚, α = 103.243(3)°, β = 109.270(4)° and γ = 87.391(2)°; (space group P1 (No. 2)). Li2NaBP2O8 consists of one-dimensional ∞1[BP2O8]3- chains of BO4 and PO4 tetrahedra in the direction of the c axis, and Li and Na atoms located around the chains. The XRD reflections of the LiNa2B5P2O14 single crystal were indexed with monoclinic unit-cell parameters of a = 8.208(3) A˚, b = 9.151(3) A˚, c = 8.349(3) A˚ and β = 115.709(7)°; (space group P21/m (No. 11)). In the crystal structure of LiNa2B5P2O14, BO3 trigonal planer and BO4 and PO4 tetrahedra share O atoms and form two-dimensional sheets of ∞2[B5P2O14]3-. One Li and two Na atoms are situated at a large triangular space in the sheets.

AB - Single crystals of Li2NaBP2O8 and LiNa2B5P2O14 were prepared at 873-883 K. The XRD reflections of Li2NaBP2O8 single crystal were indexed with triclinic unit-cell parameters of a = 5.4344(3) A˚, b = 7.3793 (4) A˚, c = 7.9840(4) A˚, α = 103.243(3)°, β = 109.270(4)° and γ = 87.391(2)°; (space group P1 (No. 2)). Li2NaBP2O8 consists of one-dimensional ∞1[BP2O8]3- chains of BO4 and PO4 tetrahedra in the direction of the c axis, and Li and Na atoms located around the chains. The XRD reflections of the LiNa2B5P2O14 single crystal were indexed with monoclinic unit-cell parameters of a = 8.208(3) A˚, b = 9.151(3) A˚, c = 8.349(3) A˚ and β = 115.709(7)°; (space group P21/m (No. 11)). In the crystal structure of LiNa2B5P2O14, BO3 trigonal planer and BO4 and PO4 tetrahedra share O atoms and form two-dimensional sheets of ∞2[B5P2O14]3-. One Li and two Na atoms are situated at a large triangular space in the sheets.

KW - Borophosphate

KW - Crystal structure

KW - Solid-state reaction

UR - http://www.scopus.com/inward/record.url?scp=84920812734&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84920812734&partnerID=8YFLogxK

U2 - 10.1016/j.jssc.2014.11.024

DO - 10.1016/j.jssc.2014.11.024

M3 - Article

AN - SCOPUS:84920812734

SN - 0022-4596

VL - 225

SP - 65

EP - 71

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

ER -