Synthesis and crystal structure of new salicylate-bridged coordination polymer, [Cu2(sal)2(pyz)(MeOH)2]n

Zhu Longguan; Susumu Kitagawa; Mitsuru Kondo; Hitoshi Miyasaka

doi:10.1246/cl.2000.536

Synthesis and crystal structure of new salicylate-bridged coordination polymer, [Cu₂(sal)₂(pyz)(MeOH)₂]_n

Zhu Longguan, Susumu Kitagawa, Mitsuru Kondo, Hitoshi Miyasaka

IMR - Materials Development Division

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The title compound, {[Cu₂(sal)₂(pyz)]·2MeOH}_n (H₂sal = salicylic acid, pyz = pyrazine) (1), has been synthesized, and structurally characterized. Each sal ligand connects the three copper centers to afford a novel 2-D network structure. The Cu^II-sal framework forms a rhombus type two-dimensional coordination framework. The pyz molecules, which fill the voids of the network, bind to the Cu site to afford zigzag chain.

Original language	English
Pages (from-to)	536-537
Number of pages	2
Journal	Chemistry Letters
Issue number	5
DOIs	https://doi.org/10.1246/cl.2000.536
Publication status	Published - 2000

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10.1246/cl.2000.536

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abstract = "The title compound, {[Cu2(sal)2(pyz)]·2MeOH}n (H2sal = salicylic acid, pyz = pyrazine) (1), has been synthesized, and structurally characterized. Each sal ligand connects the three copper centers to afford a novel 2-D network structure. The CuII-sal framework forms a rhombus type two-dimensional coordination framework. The pyz molecules, which fill the voids of the network, bind to the Cu site to afford zigzag chain.",

author = "Zhu Longguan and Susumu Kitagawa and Mitsuru Kondo and Hitoshi Miyasaka",

year = "2000",

doi = "10.1246/cl.2000.536",

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journal = "Chemistry Letters",

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T1 - Synthesis and crystal structure of new salicylate-bridged coordination polymer, [Cu2(sal)2(pyz)(MeOH)2]n

AU - Longguan, Zhu

AU - Kitagawa, Susumu

AU - Kondo, Mitsuru

AU - Miyasaka, Hitoshi

PY - 2000

Y1 - 2000

N2 - The title compound, {[Cu2(sal)2(pyz)]·2MeOH}n (H2sal = salicylic acid, pyz = pyrazine) (1), has been synthesized, and structurally characterized. Each sal ligand connects the three copper centers to afford a novel 2-D network structure. The CuII-sal framework forms a rhombus type two-dimensional coordination framework. The pyz molecules, which fill the voids of the network, bind to the Cu site to afford zigzag chain.

AB - The title compound, {[Cu2(sal)2(pyz)]·2MeOH}n (H2sal = salicylic acid, pyz = pyrazine) (1), has been synthesized, and structurally characterized. Each sal ligand connects the three copper centers to afford a novel 2-D network structure. The CuII-sal framework forms a rhombus type two-dimensional coordination framework. The pyz molecules, which fill the voids of the network, bind to the Cu site to afford zigzag chain.

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JF - Chemistry Letters

IS - 5

ER -

Synthesis and crystal structure of new salicylate-bridged coordination polymer, [Cu₂(sal)₂(pyz)(MeOH)₂]_n

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