Synthesis and double doping behavior of a poly(p-phenylenevinylene)s bearing conjugated side chains

Hirotsugu Kawashima; Kohsuke Kawabata; Hiromasa Goto

doi:10.1002/pola.25919

Synthesis and double doping behavior of a poly(p-phenylenevinylene)s bearing conjugated side chains

Hirotsugu Kawashima, Kohsuke Kawabata, Hiromasa Goto

SCI - Chemistry

University of Tsukuba

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A poly(p-phenylenevinylene) derivative bearing conjugated side chains (polyCPV) was synthesized by Migita-Kosugi-Stille type coupling polycondensation reaction. This polymer contains phenylenevinylene units in both the main chain and the side chains. UV-vis absorption and fluorescence emission spectroscopies revealed a well-developed π-conjugation of the polyCPV. The absorption band of the polymer was extended to long wavelengths. A fluorescent emission maximum of polyCPV is located at considerably longer wavelengths than that of the conjugated side chain monomer. Electron spin resonance measurements of polyCPV confirmed generation of charge species in both the main chain and the side chains via iodine doping.

Original language	English
Pages (from-to)	1530-1538
Number of pages	9
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	50
Issue number	8
DOIs	https://doi.org/10.1002/pola.25919
Publication status	Published - 2012 Apr 15

Keywords

ESR/EPR
UV-vis spectroscopy
atomic force microscopy (AFM)
conjugated polymers

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10.1002/pola.25919

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title = "Synthesis and double doping behavior of a poly(p-phenylenevinylene)s bearing conjugated side chains",

abstract = "A poly(p-phenylenevinylene) derivative bearing conjugated side chains (polyCPV) was synthesized by Migita-Kosugi-Stille type coupling polycondensation reaction. This polymer contains phenylenevinylene units in both the main chain and the side chains. UV-vis absorption and fluorescence emission spectroscopies revealed a well-developed π-conjugation of the polyCPV. The absorption band of the polymer was extended to long wavelengths. A fluorescent emission maximum of polyCPV is located at considerably longer wavelengths than that of the conjugated side chain monomer. Electron spin resonance measurements of polyCPV confirmed generation of charge species in both the main chain and the side chains via iodine doping.",

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T1 - Synthesis and double doping behavior of a poly(p-phenylenevinylene)s bearing conjugated side chains

AU - Kawashima, Hirotsugu

AU - Kawabata, Kohsuke

AU - Goto, Hiromasa

PY - 2012/4/15

Y1 - 2012/4/15

N2 - A poly(p-phenylenevinylene) derivative bearing conjugated side chains (polyCPV) was synthesized by Migita-Kosugi-Stille type coupling polycondensation reaction. This polymer contains phenylenevinylene units in both the main chain and the side chains. UV-vis absorption and fluorescence emission spectroscopies revealed a well-developed π-conjugation of the polyCPV. The absorption band of the polymer was extended to long wavelengths. A fluorescent emission maximum of polyCPV is located at considerably longer wavelengths than that of the conjugated side chain monomer. Electron spin resonance measurements of polyCPV confirmed generation of charge species in both the main chain and the side chains via iodine doping.

AB - A poly(p-phenylenevinylene) derivative bearing conjugated side chains (polyCPV) was synthesized by Migita-Kosugi-Stille type coupling polycondensation reaction. This polymer contains phenylenevinylene units in both the main chain and the side chains. UV-vis absorption and fluorescence emission spectroscopies revealed a well-developed π-conjugation of the polyCPV. The absorption band of the polymer was extended to long wavelengths. A fluorescent emission maximum of polyCPV is located at considerably longer wavelengths than that of the conjugated side chain monomer. Electron spin resonance measurements of polyCPV confirmed generation of charge species in both the main chain and the side chains via iodine doping.

KW - ESR/EPR

KW - UV-vis spectroscopy

KW - atomic force microscopy (AFM)

KW - conjugated polymers

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DO - 10.1002/pola.25919

M3 - Article

AN - SCOPUS:84858264234

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JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 8

ER -

Synthesis and double doping behavior of a poly(p-phenylenevinylene)s bearing conjugated side chains

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Keywords

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