TY - JOUR
T1 - Synthesis and dynamic behaviour of 1-(dipropylboryl)cyclohepta-2,4-diene
AU - Gridnev, Ilya D.
AU - Gurskii, Mikhail E.
AU - Geiderikh, Alexey V.
AU - Bubnov, Yurii N.
N1 - Funding Information:
This work was partly supported by the Russian Foundation for Basic Research (grant no. 94-03-08857).
PY - 1996
Y1 - 1996
N2 - Two sequential [1,3] boron shifts in 1-(dipropylboryl)cyclohepta-2,4-diene 1 result in a degenerate rearrangement (EA = 98.9±3.3 kJ mol-1, In A = 39.3±1.4, ΔG298≠ = 118.3±0.3 kJ mol-1); reaction of 1 with acetone affords non-conjugated alcohol 2.
AB - Two sequential [1,3] boron shifts in 1-(dipropylboryl)cyclohepta-2,4-diene 1 result in a degenerate rearrangement (EA = 98.9±3.3 kJ mol-1, In A = 39.3±1.4, ΔG298≠ = 118.3±0.3 kJ mol-1); reaction of 1 with acetone affords non-conjugated alcohol 2.
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U2 - 10.1070/MC1996v006n05ABEH000637
DO - 10.1070/MC1996v006n05ABEH000637
M3 - Article
AN - SCOPUS:27844525494
SN - 0959-9436
VL - 6
SP - 185
EP - 187
JO - Mendeleev Communications
JF - Mendeleev Communications
IS - 5
ER -