Synthesis and photoluminescence properties of SrLaAlO4: Ti green-emitting phosphor

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Abstract

Ti-doped SrLaAlO4 green-emitting phosphor was synthesized via solid-state reactions in air and N2 atmosphere. Sample heated in air showed no emission, however, sample heated in N2 showed broad green emission around 492 nm and broad near-infrared emission around 950 nm by 321 nm near-ultraviolet excitation. XPS measurement and UV-Vis diffuse reflectance spectra suggest that Ti in the sample was reduced to Ti3+ state when the sample was heated in N2. Possible emission mechanism of the sample can be explained as O2-–Ti3+ charge-transfer transition.

Original languageEnglish
Title of host publicationEco-Materials Processing and Design XVII
EditorsJian Feng Yang, Hyung Sun Kim, Tohru Sekino, Wen Bin Cao, Soo Wohn Lee
PublisherTrans Tech Publications Ltd
Pages1-5
Number of pages5
ISBN (Print)9783038357711
DOIs
Publication statusPublished - 2016
Event17th International Symposium on Eco-Materials Processing and Design, ISEPD 2016 - Haikou, China
Duration: 2011 Jan 82011 Jan 11

Publication series

NameMaterials Science Forum
Volume868
ISSN (Print)0255-5476
ISSN (Electronic)1662-9752

Conference

Conference17th International Symposium on Eco-Materials Processing and Design, ISEPD 2016
Country/TerritoryChina
CityHaikou
Period11/1/811/1/11

Keywords

  • Charge-transfer excitation
  • Green emission
  • Ti-doped phosphor
  • White LED

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