Synthesis and properties of bis(ethyleneseleno)tetrathiafulvalene (BES-TTF) and diselenolotetrathiafulvalene (DS-TTF) as novel electron donors

Tetsuya Jigami; Kazuo Takimiya; Yoshio Aso; Tetsuo Otsubo

doi:10.1246/cl.1997.1091

Synthesis and properties of bis(ethyleneseleno)tetrathiafulvalene (BES-TTF) and diselenolotetrathiafulvalene (DS-TTF) as novel electron donors

Tetsuya Jigami, Kazuo Takimiya, Yoshio Aso, Tetsuo Otsubo

SCI - Chemistry

Hiroshima University

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The title selenocycle-fused tetrathiafulvalene derivatives, BES-TTF and DS-TTF have been synthesized as novel electron donors, and their conductive charge-transfer complexes have been studied. All complexes of the BES-TTF compound with TCNQ, ClO₄, and PF₆ showed very high conductivities of the order of 10² S cm^-1 as well as metallic temperature-dependent behavior.

Original language	English
Pages (from-to)	1091-1092
Number of pages	2
Journal	Chemistry Letters
Issue number	11
DOIs	https://doi.org/10.1246/cl.1997.1091
Publication status	Published - 1997

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abstract = "The title selenocycle-fused tetrathiafulvalene derivatives, BES-TTF and DS-TTF have been synthesized as novel electron donors, and their conductive charge-transfer complexes have been studied. All complexes of the BES-TTF compound with TCNQ, ClO4, and PF6 showed very high conductivities of the order of 102 S cm-1 as well as metallic temperature-dependent behavior.",

author = "Tetsuya Jigami and Kazuo Takimiya and Yoshio Aso and Tetsuo Otsubo",

year = "1997",

doi = "10.1246/cl.1997.1091",

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AU - Jigami, Tetsuya

AU - Takimiya, Kazuo

AU - Aso, Yoshio

AU - Otsubo, Tetsuo

PY - 1997

Y1 - 1997

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AB - The title selenocycle-fused tetrathiafulvalene derivatives, BES-TTF and DS-TTF have been synthesized as novel electron donors, and their conductive charge-transfer complexes have been studied. All complexes of the BES-TTF compound with TCNQ, ClO4, and PF6 showed very high conductivities of the order of 102 S cm-1 as well as metallic temperature-dependent behavior.

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IS - 11

ER -

Synthesis and properties of bis(ethyleneseleno)tetrathiafulvalene (BES-TTF) and diselenolotetrathiafulvalene (DS-TTF) as novel electron donors

Abstract

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