Synthesis and properties of bitetraselenafulvalene

Masahiko Iyoda; Kenji Hara; C. R. Venkateswara Rao; Yoshiyuki Kuwatani; Kazuo Takimiya; Atsushi Morikami; Aso Yoshio; Tetsuo Otsubo

doi:10.1016/S0040-4039(99)01085-0

Synthesis and properties of bitetraselenafulvalene

Masahiko Iyoda, Kenji Hara, C. R. Venkateswara Rao, Yoshiyuki Kuwatani, Kazuo Takimiya, Atsushi Morikami, Aso Yoshio, Tetsuo Otsubo

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Copper(II)- and palladium(II)-catalyzed homo-coupling reactions of trimethylstannyltetraselenafulvalene proceed smoothly to produce bitetraselenafulvalene (biTSF) in good yield. The X-ray analysis of biTSF shows an interesting crystal structure. The CT-complex and radical cation salts derived from biTSF indicate fairly high electric conductivities.

Original language	English
Pages (from-to)	5729-5730
Number of pages	2
Journal	Tetrahedron Letters
Volume	40
Issue number	31
DOIs	https://doi.org/10.1016/S0040-4039(99)01085-0
Publication status	Published - 1999 Jul 30

Keywords

Coupling reactions
Electron donors
Physical properties
X-ray crystal structures

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10.1016/S0040-4039(99)01085-0

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title = "Synthesis and properties of bitetraselenafulvalene",

abstract = "Copper(II)- and palladium(II)-catalyzed homo-coupling reactions of trimethylstannyltetraselenafulvalene proceed smoothly to produce bitetraselenafulvalene (biTSF) in good yield. The X-ray analysis of biTSF shows an interesting crystal structure. The CT-complex and radical cation salts derived from biTSF indicate fairly high electric conductivities.",

keywords = "Coupling reactions, Electron donors, Physical properties, X-ray crystal structures",

author = "Masahiko Iyoda and Kenji Hara and {Venkateswara Rao}, {C. R.} and Yoshiyuki Kuwatani and Kazuo Takimiya and Atsushi Morikami and Aso Yoshio and Tetsuo Otsubo",

year = "1999",

month = jul,

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doi = "10.1016/S0040-4039(99)01085-0",

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TY - JOUR

T1 - Synthesis and properties of bitetraselenafulvalene

AU - Iyoda, Masahiko

AU - Hara, Kenji

AU - Venkateswara Rao, C. R.

AU - Kuwatani, Yoshiyuki

AU - Takimiya, Kazuo

AU - Morikami, Atsushi

AU - Yoshio, Aso

AU - Otsubo, Tetsuo

PY - 1999/7/30

Y1 - 1999/7/30

N2 - Copper(II)- and palladium(II)-catalyzed homo-coupling reactions of trimethylstannyltetraselenafulvalene proceed smoothly to produce bitetraselenafulvalene (biTSF) in good yield. The X-ray analysis of biTSF shows an interesting crystal structure. The CT-complex and radical cation salts derived from biTSF indicate fairly high electric conductivities.

AB - Copper(II)- and palladium(II)-catalyzed homo-coupling reactions of trimethylstannyltetraselenafulvalene proceed smoothly to produce bitetraselenafulvalene (biTSF) in good yield. The X-ray analysis of biTSF shows an interesting crystal structure. The CT-complex and radical cation salts derived from biTSF indicate fairly high electric conductivities.

KW - Coupling reactions

KW - Electron donors

KW - Physical properties

KW - X-ray crystal structures

UR - http://www.scopus.com/inward/record.url?scp=0033618293&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0033618293&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(99)01085-0

DO - 10.1016/S0040-4039(99)01085-0

M3 - Article

AN - SCOPUS:0033618293

SN - 0040-4039

VL - 40

SP - 5729

EP - 5730

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 31

ER -

Synthesis and properties of bitetraselenafulvalene

Abstract

Keywords

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