TY - JOUR
T1 - Synthesis and properties of new PDT- and TPDT-TTP analogues
AU - Kaibuki, T.
AU - Misaki, Y.
AU - Tanaka, K.
AU - Takimiya, K.
AU - Morikami, A.
AU - Otsubo, T.
N1 - Funding Information:
*Dr. Y. Misaki telephone; +8175 753 5933, fax; +8175 771 0172 atnail; misakiG&nee3.moleng.kyoto-u.ac.jp Acknowledgement; This work is partially supported by Scientific Research No. 09640687 and by Japan Society for Science-Research for the Future Program (BPS-RiTF96P00206).
PY - 1999/6
Y1 - 1999/6
N2 - 2-(1,3-Diselenol-2-ylidene)-5-(pyran-4-ylidene)- 1,3,4,6-tetrathiapentalene (PDS-TTP), its thiopyran analogue (TPDS-TTP), and their bis(methylthio) derivatives have been prepared. Their first and second oxidation potentials are comparable to those of the corresponding sulfur analogues. The PF6 and AsF6 salt of PDS-TTP displayed metallic conductivity down to 4.2 K, and TCNQ complex was semiconductor with a low activation energy (0.006 eV).
AB - 2-(1,3-Diselenol-2-ylidene)-5-(pyran-4-ylidene)- 1,3,4,6-tetrathiapentalene (PDS-TTP), its thiopyran analogue (TPDS-TTP), and their bis(methylthio) derivatives have been prepared. Their first and second oxidation potentials are comparable to those of the corresponding sulfur analogues. The PF6 and AsF6 salt of PDS-TTP displayed metallic conductivity down to 4.2 K, and TCNQ complex was semiconductor with a low activation energy (0.006 eV).
UR - http://www.scopus.com/inward/record.url?scp=0033137650&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0033137650&partnerID=8YFLogxK
U2 - 10.1016/S0379-6779(98)00469-X
DO - 10.1016/S0379-6779(98)00469-X
M3 - Conference article
AN - SCOPUS:0033137650
SN - 0379-6779
VL - 102
SP - 1621
EP - 1622
JO - Synthetic Metals
JF - Synthetic Metals
IS - 1-3
T2 - Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98)
Y2 - 12 July 1998 through 18 July 1998
ER -