Synthesis and stereochemical confirmation of the cis-fused L/M and N/O ring systems of maitotoxin

Makoto Sasaki; Taro Nonomura; Michio Murata; Kazuo Tachibana

doi:10.1016/S0040-4039(00)73310-7

Synthesis and stereochemical confirmation of the cis-fused L/M and N/O ring systems of maitotoxin

Makoto Sasaki, Taro Nonomura, Michio Murata, Kazuo Tachibana

LIF - Molecular and Chemical Life Science

The University of Tokyo

Research output: Contribution to journal › Article › peer-review

53 Citations (Scopus)

Abstract

Stereocontrolled synthesis of cis-fused 1,6-dioxadecalin system 1, which corresponds to the L/M and N/O rings of maitotoxin, was accomplished. Comparison of its ¹H and ¹³C NMR data with those of the natural toxin established the earlier stereochemical assignments.

Original language	English
Pages (from-to)	5023-5026
Number of pages	4
Journal	Tetrahedron Letters
Volume	35
Issue number	28
DOIs	https://doi.org/10.1016/S0040-4039(00)73310-7
Publication status	Published - 1994 Jul 11

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10.1016/S0040-4039(00)73310-7

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abstract = "Stereocontrolled synthesis of cis-fused 1,6-dioxadecalin system 1, which corresponds to the L/M and N/O rings of maitotoxin, was accomplished. Comparison of its 1H and 13C NMR data with those of the natural toxin established the earlier stereochemical assignments.",

author = "Makoto Sasaki and Taro Nonomura and Michio Murata and Kazuo Tachibana",

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AU - Murata, Michio

AU - Tachibana, Kazuo

PY - 1994/7/11

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AB - Stereocontrolled synthesis of cis-fused 1,6-dioxadecalin system 1, which corresponds to the L/M and N/O rings of maitotoxin, was accomplished. Comparison of its 1H and 13C NMR data with those of the natural toxin established the earlier stereochemical assignments.

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Synthesis and stereochemical confirmation of the cis-fused L/M and N/O ring systems of maitotoxin

Abstract

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