Synthesis and structure of 1-phospholyl- and di(1-phospholyl)acetylenes and the corresponding sulfides

Shigeru Sasaki; Takashi Mori; Masaaki Yoshifuji

doi:10.1002/hc.20230

Synthesis and structure of 1-phospholyl- and di(1-phospholyl)acetylenes and the corresponding sulfides

Shigeru Sasaki, Takashi Mori, Masaaki Yoshifuji

SCI - Chemistry

Tohoku University

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The acetylenes possessing one and two 1-phospholyl groups were synthesized by reaction of the alkynyl Grignard reagents with the 1-chlorophosphole and converted to the corresponding phosphole sulfides. Reaction of the 1-phenylethynylphosphole sulfide with CpCo(CO)₂ resulted in η⁴-complexation on the phosphate moiety. The structures of the di(1-phospholyl)acetylene disulfide and the [η⁴-(1- phenylethynylphosphole sulfide)]cobalt(I) complex were characterized by X-ray crystallography.

Original language	English
Pages (from-to)	344-349
Number of pages	6
Journal	Heteroatom Chemistry
Volume	17
Issue number	4
DOIs	https://doi.org/10.1002/hc.20230
Publication status	Published - 2006

Access to Document

10.1002/hc.20230

Cite this

@article{c926fa1e208644b28c1b27ddaf0889c5,

title = "Synthesis and structure of 1-phospholyl- and di(1-phospholyl)acetylenes and the corresponding sulfides",

abstract = "The acetylenes possessing one and two 1-phospholyl groups were synthesized by reaction of the alkynyl Grignard reagents with the 1-chlorophosphole and converted to the corresponding phosphole sulfides. Reaction of the 1-phenylethynylphosphole sulfide with CpCo(CO)2 resulted in η4-complexation on the phosphate moiety. The structures of the di(1-phospholyl)acetylene disulfide and the [η4-(1- phenylethynylphosphole sulfide)]cobalt(I) complex were characterized by X-ray crystallography.",

author = "Shigeru Sasaki and Takashi Mori and Masaaki Yoshifuji",

year = "2006",

doi = "10.1002/hc.20230",

language = "English",

volume = "17",

pages = "344--349",

journal = "Heteroatom Chemistry",

issn = "1042-7163",

publisher = "Wiley-Blackwell",

number = "4",

}

TY - JOUR

T1 - Synthesis and structure of 1-phospholyl- and di(1-phospholyl)acetylenes and the corresponding sulfides

AU - Sasaki, Shigeru

AU - Mori, Takashi

AU - Yoshifuji, Masaaki

PY - 2006

Y1 - 2006

N2 - The acetylenes possessing one and two 1-phospholyl groups were synthesized by reaction of the alkynyl Grignard reagents with the 1-chlorophosphole and converted to the corresponding phosphole sulfides. Reaction of the 1-phenylethynylphosphole sulfide with CpCo(CO)2 resulted in η4-complexation on the phosphate moiety. The structures of the di(1-phospholyl)acetylene disulfide and the [η4-(1- phenylethynylphosphole sulfide)]cobalt(I) complex were characterized by X-ray crystallography.

AB - The acetylenes possessing one and two 1-phospholyl groups were synthesized by reaction of the alkynyl Grignard reagents with the 1-chlorophosphole and converted to the corresponding phosphole sulfides. Reaction of the 1-phenylethynylphosphole sulfide with CpCo(CO)2 resulted in η4-complexation on the phosphate moiety. The structures of the di(1-phospholyl)acetylene disulfide and the [η4-(1- phenylethynylphosphole sulfide)]cobalt(I) complex were characterized by X-ray crystallography.

UR - http://www.scopus.com/inward/record.url?scp=33744456480&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33744456480&partnerID=8YFLogxK

U2 - 10.1002/hc.20230

DO - 10.1002/hc.20230

M3 - Article

AN - SCOPUS:33744456480

SN - 1042-7163

VL - 17

SP - 344

EP - 349

JO - Heteroatom Chemistry

JF - Heteroatom Chemistry

IS - 4

ER -

Synthesis and structure of 1-phospholyl- and di(1-phospholyl)acetylenes and the corresponding sulfides

Abstract

Access to Document

Other files and links

Fingerprint

Cite this