Synthesis and structure of a hydrido(hydrosilylene)ruthenium complex and its reactions with nitriles

Mitsuyoshi Ochiai; Hisako Hashimoto; Hiromi Tobita

doi:10.1002/anie.200703154

Synthesis and structure of a hydrido(hydrosilylene)ruthenium complex and its reactions with nitriles

Mitsuyoshi Ochiai, Hisako Hashimoto, Hiromi Tobita

Research output: Contribution to journal › Article › peer-review

96 Citations (Scopus)

Abstract

(Chemical Equation Presented) Ring around the Ru=Si: Abstraction of a pyridine ligand with BPh₃ was used to synthesize the silylene complex 1 (see scheme), which reacts with nitriles at room temperature to give silylisocyanide complex 3 by C-C bond activation. The structure of key intermediate 2 with an η²-Si-H agostic interaction is given along with mechanisms for the formation of 2 and 3.

Original language	English
Pages (from-to)	8192-8194
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	43
DOIs	https://doi.org/10.1002/anie.200703154
Publication status	Published - 2007 Nov 19

Keywords

Agostic interactions
C-C activation
Rearrangement
Ruthenium
Silicon

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.200703154

Cite this

@article{5105019deb634b1bb23d7ce143784816,

title = "Synthesis and structure of a hydrido(hydrosilylene)ruthenium complex and its reactions with nitriles",

abstract = "(Chemical Equation Presented) Ring around the Ru=Si: Abstraction of a pyridine ligand with BPh3 was used to synthesize the silylene complex 1 (see scheme), which reacts with nitriles at room temperature to give silylisocyanide complex 3 by C-C bond activation. The structure of key intermediate 2 with an η2-Si-H agostic interaction is given along with mechanisms for the formation of 2 and 3.",

keywords = "Agostic interactions, C-C activation, Rearrangement, Ruthenium, Silicon",

author = "Mitsuyoshi Ochiai and Hisako Hashimoto and Hiromi Tobita",

year = "2007",

month = nov,

day = "19",

doi = "10.1002/anie.200703154",

language = "English",

volume = "46",

pages = "8192--8194",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "43",

}

TY - JOUR

T1 - Synthesis and structure of a hydrido(hydrosilylene)ruthenium complex and its reactions with nitriles

AU - Ochiai, Mitsuyoshi

AU - Hashimoto, Hisako

AU - Tobita, Hiromi

PY - 2007/11/19

Y1 - 2007/11/19

N2 - (Chemical Equation Presented) Ring around the Ru=Si: Abstraction of a pyridine ligand with BPh3 was used to synthesize the silylene complex 1 (see scheme), which reacts with nitriles at room temperature to give silylisocyanide complex 3 by C-C bond activation. The structure of key intermediate 2 with an η2-Si-H agostic interaction is given along with mechanisms for the formation of 2 and 3.

AB - (Chemical Equation Presented) Ring around the Ru=Si: Abstraction of a pyridine ligand with BPh3 was used to synthesize the silylene complex 1 (see scheme), which reacts with nitriles at room temperature to give silylisocyanide complex 3 by C-C bond activation. The structure of key intermediate 2 with an η2-Si-H agostic interaction is given along with mechanisms for the formation of 2 and 3.

KW - Agostic interactions

KW - C-C activation

KW - Rearrangement

KW - Ruthenium

KW - Silicon

UR - http://www.scopus.com/inward/record.url?scp=36048960728&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=36048960728&partnerID=8YFLogxK

U2 - 10.1002/anie.200703154

DO - 10.1002/anie.200703154

M3 - Article

C2 - 17886823

AN - SCOPUS:36048960728

SN - 1433-7851

VL - 46

SP - 8192

EP - 8194

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 43

ER -

Synthesis and structure of a hydrido(hydrosilylene)ruthenium complex and its reactions with nitriles

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this