Synthesis and structure of a stable cyclic dialkylgermylene

Mitsuo Kira; Shintaro Ishida; Takeaki Iwamoto; Masaaki Ichinohe; Chizuko Kabuto; Lubov Ignatovich; Hideki Sakurai

doi:10.1246/cl.1999.263

Synthesis and structure of a stable cyclic dialkylgermylene

Mitsuo Kira, Shintaro Ishida, Takeaki Iwamoto, Masaaki Ichinohe, Chizuko Kabuto, Lubov Ignatovich, Hideki Sakurai

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

68 Citations (Scopus)

Abstract

A stable cyclic dialkylgermylene (1) was synthesized by reductive dechlorination of the corresponding dichlorogermane (6) with sodium. Germylene 1 is monomeric both in solution and in the solid state, as observed by UV-vis spectroscopy and X-ray crystallography.

Original language	English
Pages (from-to)	263-264
Number of pages	2
Journal	Chemistry Letters
Issue number	3
DOIs	https://doi.org/10.1246/cl.1999.263
Publication status	Published - 1999

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10.1246/cl.1999.263

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title = "Synthesis and structure of a stable cyclic dialkylgermylene",

abstract = "A stable cyclic dialkylgermylene (1) was synthesized by reductive dechlorination of the corresponding dichlorogermane (6) with sodium. Germylene 1 is monomeric both in solution and in the solid state, as observed by UV-vis spectroscopy and X-ray crystallography.",

author = "Mitsuo Kira and Shintaro Ishida and Takeaki Iwamoto and Masaaki Ichinohe and Chizuko Kabuto and Lubov Ignatovich and Hideki Sakurai",

year = "1999",

doi = "10.1246/cl.1999.263",

language = "English",

pages = "263--264",

journal = "Chemistry Letters",

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publisher = "The Chemical Society of Japan",

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T1 - Synthesis and structure of a stable cyclic dialkylgermylene

AU - Kira, Mitsuo

AU - Ishida, Shintaro

AU - Iwamoto, Takeaki

AU - Ichinohe, Masaaki

AU - Kabuto, Chizuko

AU - Ignatovich, Lubov

AU - Sakurai, Hideki

PY - 1999

Y1 - 1999

N2 - A stable cyclic dialkylgermylene (1) was synthesized by reductive dechlorination of the corresponding dichlorogermane (6) with sodium. Germylene 1 is monomeric both in solution and in the solid state, as observed by UV-vis spectroscopy and X-ray crystallography.

AB - A stable cyclic dialkylgermylene (1) was synthesized by reductive dechlorination of the corresponding dichlorogermane (6) with sodium. Germylene 1 is monomeric both in solution and in the solid state, as observed by UV-vis spectroscopy and X-ray crystallography.

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U2 - 10.1246/cl.1999.263

DO - 10.1246/cl.1999.263

M3 - Article

AN - SCOPUS:0033246944

SN - 0366-7022

SP - 263

EP - 264

JO - Chemistry Letters

JF - Chemistry Letters

IS - 3

ER -

Synthesis and structure of a stable cyclic dialkylgermylene

Abstract

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