Synthesis and Structure of the First Donor-Stabilized Bls(silyleπe)manganese Complex

Tamiko Takeuchi; Hiromi Tobita; Hiroshi Ogino

doi:10.1021/om00050a006

Synthesis and Structure of the First Donor-Stabilized Bls(silyleπe)manganese Complex

Tamiko Takeuchi, Hiromi Tobita, Hiroshi Ogino

Institute for Excellence in Higher Education (IEHE) (organization affiliation only)

Research output: Contribution to journal › Letter › peer-review

53 Citations (Scopus)

Abstract

The first manganese derivative of the donor-stabilized bis(silylene) complex (OC)₄Mn{SiMe₂⋯O(Me)⋯ SiMe₂} has been synthesized by the photolysis of (OC)₅MnSiMe₂SiMe₂OMe. The X-ray structure analysis of this complex revealed its distorted-octahedral structure with two short Mn-Si bonds and a planar MnSi₂O chelate ring.

Original language	English
Pages (from-to)	835-836
Number of pages	2
Journal	Organometallics
Volume	10
Issue number	4
DOIs	https://doi.org/10.1021/om00050a006
Publication status	Published - 1991 Apr 1

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1021/om00050a006

Cite this

@article{50ca7cfc7546461bae22b49ba9efa5bd,

title = "Synthesis and Structure of the First Donor-Stabilized Bls(silyleπe)manganese Complex",

abstract = "The first manganese derivative of the donor-stabilized bis(silylene) complex (OC)4Mn{SiMe2⋯O(Me)⋯ SiMe2} has been synthesized by the photolysis of (OC)5MnSiMe2SiMe2OMe. The X-ray structure analysis of this complex revealed its distorted-octahedral structure with two short Mn-Si bonds and a planar MnSi2O chelate ring.",

author = "Tamiko Takeuchi and Hiromi Tobita and Hiroshi Ogino",

year = "1991",

month = apr,

day = "1",

doi = "10.1021/om00050a006",

language = "English",

volume = "10",

pages = "835--836",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "4",

}

TY - JOUR

T1 - Synthesis and Structure of the First Donor-Stabilized Bls(silyleπe)manganese Complex

AU - Takeuchi, Tamiko

AU - Tobita, Hiromi

AU - Ogino, Hiroshi

PY - 1991/4/1

Y1 - 1991/4/1

N2 - The first manganese derivative of the donor-stabilized bis(silylene) complex (OC)4Mn{SiMe2⋯O(Me)⋯ SiMe2} has been synthesized by the photolysis of (OC)5MnSiMe2SiMe2OMe. The X-ray structure analysis of this complex revealed its distorted-octahedral structure with two short Mn-Si bonds and a planar MnSi2O chelate ring.

AB - The first manganese derivative of the donor-stabilized bis(silylene) complex (OC)4Mn{SiMe2⋯O(Me)⋯ SiMe2} has been synthesized by the photolysis of (OC)5MnSiMe2SiMe2OMe. The X-ray structure analysis of this complex revealed its distorted-octahedral structure with two short Mn-Si bonds and a planar MnSi2O chelate ring.

UR - http://www.scopus.com/inward/record.url?scp=0000301789&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000301789&partnerID=8YFLogxK

U2 - 10.1021/om00050a006

DO - 10.1021/om00050a006

M3 - Letter

AN - SCOPUS:0000301789

SN - 0276-7333

VL - 10

SP - 835

EP - 836

JO - Organometallics

JF - Organometallics

IS - 4

ER -

Synthesis and Structure of the First Donor-Stabilized Bls(silyleπe)manganese Complex

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this