Synthesis and structures of heterometallic trinuclear clusters [CpFe(CO)2]2(μ3-S2)W(CO)5 and Cp2Fe2(CO)3(μ-CO)(μ3-S)W(CO)5 and kinetic study of migration of the W(CO)5 moiety in the disulfido complex

Katsuaki Kuge; Hiromi Tobita; Hiroshi Ogino

doi:10.1039/a901660k

Synthesis and structures of heterometallic trinuclear clusters [CpFe(CO)₂]₂(μ₃-S₂)W(CO)₅ and Cp₂Fe₂(CO)₃(μ-CO)(μ₃-S)W(CO)₅ and kinetic study of migration of the W(CO)₅ moiety in the disulfido complex

Katsuaki Kuge, Hiromi Tobita, Hiroshi Ogino

Institute for Excellence in Higher Education (IEHE) (organization affiliation only)

Research output: Contribution to journal › Short survey › peer-review

Abstract

The reaction of CpFe(CO)₂Br, NaSH and W(CO)₅(THF) gave two Fe₂W clusters, one with a μ₃-S₂ and the other with a μ₃-S; in the former cluster W(CO)₅ moiety migration on the disulfido ligand was observed by variable-temperature ¹H NMR spectroscopy.

Original language	English
Pages (from-to)	1061-1062
Number of pages	2
Journal	Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/a901660k
Publication status	Published - 1999 Jun 21

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a901660k

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Synthesis and structures of heterometallic trinuclear clusters [CpFe(CO)₂]₂(μ₃-S₂)W(CO)₅ and Cp₂Fe₂(CO)₃(μ-CO)(μ₃-S)W(CO)₅ and kinetic study of migration of the W(CO)₅ moiety in the disulfido complex. / Kuge, Katsuaki; Tobita, Hiromi; Ogino, Hiroshi.
In: Chemical Communications, No. 12, 21.06.1999, p. 1061-1062.

Research output: Contribution to journal › Short survey › peer-review

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title = "Synthesis and structures of heterometallic trinuclear clusters [CpFe(CO)2]2(μ3-S2)W(CO)5 and Cp2Fe2(CO)3(μ-CO)(μ3-S)W(CO)5 and kinetic study of migration of the W(CO)5 moiety in the disulfido complex",

abstract = "The reaction of CpFe(CO)2Br, NaSH and W(CO)5(THF) gave two Fe2W clusters, one with a μ3-S2 and the other with a μ3-S; in the former cluster W(CO)5 moiety migration on the disulfido ligand was observed by variable-temperature 1H NMR spectroscopy.",

author = "Katsuaki Kuge and Hiromi Tobita and Hiroshi Ogino",

year = "1999",

month = jun,

day = "21",

doi = "10.1039/a901660k",

language = "English",

pages = "1061--1062",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Synthesis and structures of heterometallic trinuclear clusters [CpFe(CO)2]2(μ3-S2)W(CO)5 and Cp2Fe2(CO)3(μ-CO)(μ3-S)W(CO)5 and kinetic study of migration of the W(CO)5 moiety in the disulfido complex

AU - Kuge, Katsuaki

AU - Tobita, Hiromi

AU - Ogino, Hiroshi

PY - 1999/6/21

Y1 - 1999/6/21

N2 - The reaction of CpFe(CO)2Br, NaSH and W(CO)5(THF) gave two Fe2W clusters, one with a μ3-S2 and the other with a μ3-S; in the former cluster W(CO)5 moiety migration on the disulfido ligand was observed by variable-temperature 1H NMR spectroscopy.

AB - The reaction of CpFe(CO)2Br, NaSH and W(CO)5(THF) gave two Fe2W clusters, one with a μ3-S2 and the other with a μ3-S; in the former cluster W(CO)5 moiety migration on the disulfido ligand was observed by variable-temperature 1H NMR spectroscopy.

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Synthesis and structures of heterometallic trinuclear clusters [CpFe(CO)₂]₂(μ₃-S₂)W(CO)₅ and Cp₂Fe₂(CO)₃(μ-CO)(μ₃-S)W(CO)₅ and kinetic study of migration of the W(CO)₅ moiety in the disulfido complex

Abstract

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