Synthesis and X-ray structure of a platinum η2-disilene complex

Hisako Hashimoto; Yohei Sekiguchi; Takeaki Iwamoto; Chizuko Kabuto; Mitsuo Kira

doi:10.1021/om010914+

Synthesis and X-ray structure of a platinum η²-disilene complex

Hisako Hashimoto, Yohei Sekiguchi, Takeaki Iwamoto, Chizuko Kabuto, Mitsuo Kira

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

The molecular structure and chemical synthesis of a platinum silyl-substituted η²-disilene complex were investigated. The structure parameters around the disilene moiety were determined by x-ray crystallography. The x-ray diffraction analysis results revealed that the disilene complex can be regarded as a metalladisilacyclopropane with a very weak π-complex character.

Original language	English
Pages (from-to)	454-456
Number of pages	3
Journal	Organometallics
Volume	21
Issue number	3
DOIs	https://doi.org/10.1021/om010914+
Publication status	Published - 2002 Feb 4

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om010914+

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abstract = "The molecular structure and chemical synthesis of a platinum silyl-substituted η2-disilene complex were investigated. The structure parameters around the disilene moiety were determined by x-ray crystallography. The x-ray diffraction analysis results revealed that the disilene complex can be regarded as a metalladisilacyclopropane with a very weak π-complex character.",

author = "Hisako Hashimoto and Yohei Sekiguchi and Takeaki Iwamoto and Chizuko Kabuto and Mitsuo Kira",

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AU - Hashimoto, Hisako

AU - Sekiguchi, Yohei

AU - Iwamoto, Takeaki

AU - Kabuto, Chizuko

AU - Kira, Mitsuo

PY - 2002/2/4

Y1 - 2002/2/4

N2 - The molecular structure and chemical synthesis of a platinum silyl-substituted η2-disilene complex were investigated. The structure parameters around the disilene moiety were determined by x-ray crystallography. The x-ray diffraction analysis results revealed that the disilene complex can be regarded as a metalladisilacyclopropane with a very weak π-complex character.

AB - The molecular structure and chemical synthesis of a platinum silyl-substituted η2-disilene complex were investigated. The structure parameters around the disilene moiety were determined by x-ray crystallography. The x-ray diffraction analysis results revealed that the disilene complex can be regarded as a metalladisilacyclopropane with a very weak π-complex character.

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Synthesis and X-ray structure of a platinum η²-disilene complex

Abstract

ASJC Scopus subject areas

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