Synthesis of a base-stabilized (Chlorogermyl)metallogermylene and its photochemical conversion to a (Chlorogermyl)germylyne complex

Shin Ya Tashita; Takahito Watanabe; Hiromi Tobita

doi:10.1246/cl.2013.43

Synthesis of a base-stabilized (Chlorogermyl)metallogermylene and its photochemical conversion to a (Chlorogermyl)germylyne complex

Shin Ya Tashita, Takahito Watanabe, Hiromi Tobita

IEHE - Institute for Excellence in Higher Education (organization affiliation only)

Tohoku University

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

An NHC-stabilized (chlorogermyl)metallogermylene [Cp- (CO) ₃WGe{GeCl(Mes)₂}(MeIiPr)] (NHC: N-heterocyclic carbene, MeIiPr: 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene, Mes: mesityl) was synthesized by the reaction of [Na(dme)2]- [CpW(CO)₃] (dme: 1,2-dimethoxyethane) with (chlorogermyl)- chlorogermylene [GeCl{GeCl(Mes) ₂}(MeIiPr)]. Irradiation to a solution of the metallogermylene with an Hg lamp afforded an NHC-stabilized (chlorogermyl)germylyne complex [Cp- (CO)₂W=Ge{GeCl(Mes)₂}(MeIiPr)].

Original language	English
Pages (from-to)	43-44
Number of pages	2
Journal	Chemistry Letters
Volume	42
Issue number	1
DOIs	https://doi.org/10.1246/cl.2013.43
Publication status	Published - 2013 Jan

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title = "Synthesis of a base-stabilized (Chlorogermyl)metallogermylene and its photochemical conversion to a (Chlorogermyl)germylyne complex",

abstract = "An NHC-stabilized (chlorogermyl)metallogermylene [Cp- (CO) 3WGe{GeCl(Mes)2}(MeIiPr)] (NHC: N-heterocyclic carbene, MeIiPr: 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene, Mes: mesityl) was synthesized by the reaction of [Na(dme)2]- [CpW(CO)3] (dme: 1,2-dimethoxyethane) with (chlorogermyl)- chlorogermylene [GeCl{GeCl(Mes) 2}(MeIiPr)]. Irradiation to a solution of the metallogermylene with an Hg lamp afforded an NHC-stabilized (chlorogermyl)germylyne complex [Cp- (CO)2W=Ge{GeCl(Mes)2}(MeIiPr)].",

author = "Tashita, {Shin Ya} and Takahito Watanabe and Hiromi Tobita",

year = "2013",

month = jan,

doi = "10.1246/cl.2013.43",

language = "English",

volume = "42",

pages = "43--44",

journal = "Chemistry Letters",

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T1 - Synthesis of a base-stabilized (Chlorogermyl)metallogermylene and its photochemical conversion to a (Chlorogermyl)germylyne complex

AU - Tashita, Shin Ya

AU - Watanabe, Takahito

AU - Tobita, Hiromi

PY - 2013/1

Y1 - 2013/1

N2 - An NHC-stabilized (chlorogermyl)metallogermylene [Cp- (CO) 3WGe{GeCl(Mes)2}(MeIiPr)] (NHC: N-heterocyclic carbene, MeIiPr: 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene, Mes: mesityl) was synthesized by the reaction of [Na(dme)2]- [CpW(CO)3] (dme: 1,2-dimethoxyethane) with (chlorogermyl)- chlorogermylene [GeCl{GeCl(Mes) 2}(MeIiPr)]. Irradiation to a solution of the metallogermylene with an Hg lamp afforded an NHC-stabilized (chlorogermyl)germylyne complex [Cp- (CO)2W=Ge{GeCl(Mes)2}(MeIiPr)].

AB - An NHC-stabilized (chlorogermyl)metallogermylene [Cp- (CO) 3WGe{GeCl(Mes)2}(MeIiPr)] (NHC: N-heterocyclic carbene, MeIiPr: 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene, Mes: mesityl) was synthesized by the reaction of [Na(dme)2]- [CpW(CO)3] (dme: 1,2-dimethoxyethane) with (chlorogermyl)- chlorogermylene [GeCl{GeCl(Mes) 2}(MeIiPr)]. Irradiation to a solution of the metallogermylene with an Hg lamp afforded an NHC-stabilized (chlorogermyl)germylyne complex [Cp- (CO)2W=Ge{GeCl(Mes)2}(MeIiPr)].

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 1

ER -

Synthesis of a base-stabilized (Chlorogermyl)metallogermylene and its photochemical conversion to a (Chlorogermyl)germylyne complex

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