Synthesis of a dialumene-benzene adduct and its reactivity as a synthetic equivalent of a dialumene

Tomohiro Agou; Koichi Nagata; Norihiro Tokitoh

doi:10.1002/anie.201305228

Synthesis of a dialumene-benzene adduct and its reactivity as a synthetic equivalent of a dialumene

Tomohiro Agou, Koichi Nagata, Norihiro Tokitoh

SCI - Chemistry

Kyoto University

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

Bonding with Al: Treatment of a dialumene-benzene adduct (1) with naphthalene and anthracene afforded the corresponding dialumene-arene adducts at room temperature. A 1,2-dialuminacyclobutene derivative was also obtained by the exchange of the C₆H₆ moiety of 1 with bis(trimethylsilyl)acetylene. These findings exhibit the potential of 1 as a synthetic equivalent of a dialumene.

Original language	English
Pages (from-to)	10818-10821
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	41
DOIs	https://doi.org/10.1002/anie.201305228
Publication status	Published - 2013 Oct 4

Keywords

alkynes
aluminum
arenes
cycloaddition
structure elucidation

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10.1002/anie.201305228

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abstract = "Bonding with Al: Treatment of a dialumene-benzene adduct (1) with naphthalene and anthracene afforded the corresponding dialumene-arene adducts at room temperature. A 1,2-dialuminacyclobutene derivative was also obtained by the exchange of the C6H6 moiety of 1 with bis(trimethylsilyl)acetylene. These findings exhibit the potential of 1 as a synthetic equivalent of a dialumene.",

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AU - Nagata, Koichi

AU - Tokitoh, Norihiro

PY - 2013/10/4

Y1 - 2013/10/4

N2 - Bonding with Al: Treatment of a dialumene-benzene adduct (1) with naphthalene and anthracene afforded the corresponding dialumene-arene adducts at room temperature. A 1,2-dialuminacyclobutene derivative was also obtained by the exchange of the C6H6 moiety of 1 with bis(trimethylsilyl)acetylene. These findings exhibit the potential of 1 as a synthetic equivalent of a dialumene.

AB - Bonding with Al: Treatment of a dialumene-benzene adduct (1) with naphthalene and anthracene afforded the corresponding dialumene-arene adducts at room temperature. A 1,2-dialuminacyclobutene derivative was also obtained by the exchange of the C6H6 moiety of 1 with bis(trimethylsilyl)acetylene. These findings exhibit the potential of 1 as a synthetic equivalent of a dialumene.

KW - alkynes

KW - aluminum

KW - arenes

KW - cycloaddition

KW - structure elucidation

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JF - Angewandte Chemie - International Edition

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Synthesis of a dialumene-benzene adduct and its reactivity as a synthetic equivalent of a dialumene

Abstract

Keywords

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