Synthesis of blue-emitting (K 1-xNa x)Mg 4(PO 4)3:Eu 2+ phosphors

Sun Woog Kim; Takuya Hasegawa; Tadashi Ishigaki; Kazuyoshi Uematsu; Mineo Sato; Kenji Toda

doi:10.1080/15980316.2014.907213

Synthesis of blue-emitting (K _1-xNa _x)Mg ₄(PO ₄)₃:Eu ²⁺ phosphors

Sun Woog Kim, Takuya Hasegawa, Tadashi Ishigaki, Kazuyoshi Uematsu, Mineo Sato, Kenji Toda

IMRAM - Division of Inorganic Material Research

Niigata University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Blue-emitting (K _1-xNa _x)Mg ₄(PO ₄)₃:Eu ²⁺ phosphors were synthesized through a conventional solid-state reaction method, and their photoluminescence properties were characterized. These phosphors exhibited the typical emission band assigned to the transition from 4f⁶5d¹ to 4f⁷ of Eu²⁺, and the emission intensity was effectively enhanced by Na ⁺-doping into the host lattice. The highest blue emission peak intensity was obtained for (K _0.65Na _0.35)Mg ₄(PO ₄)₃:1 mol%Eu²⁺, where the relative emission peak intensity was 33% of that for the commercial blue-emitting BaMgAl ₁₀O ₁₇:10 mol%Eu ²⁺ phosphor. In addition, these phosphors have excellent thermal stability in the temperature quenching effect.

Original language	English
Pages (from-to)	53-57
Number of pages	5
Journal	Journal of Information Display
Volume	15
Issue number	2
DOIs	https://doi.org/10.1080/15980316.2014.907213
Publication status	Published - 2014 Apr

Keywords

blue-emitting phosphor
solid-state reaction method

Access to Document

10.1080/15980316.2014.907213

Cite this

@article{08faeb3b0a9b40bb9ebfeee17e51bb3e,

title = "Synthesis of blue-emitting (K 1-xNa x)Mg 4(PO 4)3:Eu 2+ phosphors",

abstract = "Blue-emitting (K 1-xNa x)Mg 4(PO 4)3:Eu 2+ phosphors were synthesized through a conventional solid-state reaction method, and their photoluminescence properties were characterized. These phosphors exhibited the typical emission band assigned to the transition from 4f65d1 to 4f7 of Eu2+, and the emission intensity was effectively enhanced by Na +-doping into the host lattice. The highest blue emission peak intensity was obtained for (K 0.65Na 0.35)Mg 4(PO 4)3:1 mol%Eu2+, where the relative emission peak intensity was 33% of that for the commercial blue-emitting BaMgAl 10O 17:10 mol%Eu 2+ phosphor. In addition, these phosphors have excellent thermal stability in the temperature quenching effect.",

keywords = "blue-emitting phosphor, solid-state reaction method",

author = "Kim, {Sun Woog} and Takuya Hasegawa and Tadashi Ishigaki and Kazuyoshi Uematsu and Mineo Sato and Kenji Toda",

note = "Funding Information: This work was supported by NEDO{\textquoteright}s (New Energy and Industrial Technology Development Organization) Rare Metal Substitute Materials Development Project (“Development of a Technology for Reducing Tb and Eu Usage in Phosphors for Fluorescent Lamps through High-Speed Material Synthesis and Evaluation”).",

year = "2014",

month = apr,

doi = "10.1080/15980316.2014.907213",

language = "English",

volume = "15",

pages = "53--57",

journal = "Journal of Information Display",

issn = "1598-0316",

publisher = "Taylor and Francis Ltd.",

number = "2",

}

TY - JOUR

T1 - Synthesis of blue-emitting (K 1-xNa x)Mg 4(PO 4)3:Eu 2+ phosphors

AU - Kim, Sun Woog

AU - Hasegawa, Takuya

AU - Ishigaki, Tadashi

AU - Uematsu, Kazuyoshi

AU - Sato, Mineo

AU - Toda, Kenji

N1 - Funding Information: This work was supported by NEDO’s (New Energy and Industrial Technology Development Organization) Rare Metal Substitute Materials Development Project (“Development of a Technology for Reducing Tb and Eu Usage in Phosphors for Fluorescent Lamps through High-Speed Material Synthesis and Evaluation”).

PY - 2014/4

Y1 - 2014/4

N2 - Blue-emitting (K 1-xNa x)Mg 4(PO 4)3:Eu 2+ phosphors were synthesized through a conventional solid-state reaction method, and their photoluminescence properties were characterized. These phosphors exhibited the typical emission band assigned to the transition from 4f65d1 to 4f7 of Eu2+, and the emission intensity was effectively enhanced by Na +-doping into the host lattice. The highest blue emission peak intensity was obtained for (K 0.65Na 0.35)Mg 4(PO 4)3:1 mol%Eu2+, where the relative emission peak intensity was 33% of that for the commercial blue-emitting BaMgAl 10O 17:10 mol%Eu 2+ phosphor. In addition, these phosphors have excellent thermal stability in the temperature quenching effect.

AB - Blue-emitting (K 1-xNa x)Mg 4(PO 4)3:Eu 2+ phosphors were synthesized through a conventional solid-state reaction method, and their photoluminescence properties were characterized. These phosphors exhibited the typical emission band assigned to the transition from 4f65d1 to 4f7 of Eu2+, and the emission intensity was effectively enhanced by Na +-doping into the host lattice. The highest blue emission peak intensity was obtained for (K 0.65Na 0.35)Mg 4(PO 4)3:1 mol%Eu2+, where the relative emission peak intensity was 33% of that for the commercial blue-emitting BaMgAl 10O 17:10 mol%Eu 2+ phosphor. In addition, these phosphors have excellent thermal stability in the temperature quenching effect.

KW - blue-emitting phosphor

KW - solid-state reaction method

UR - http://www.scopus.com/inward/record.url?scp=84901813443&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84901813443&partnerID=8YFLogxK

U2 - 10.1080/15980316.2014.907213

DO - 10.1080/15980316.2014.907213

M3 - Article

AN - SCOPUS:84901813443

SN - 1598-0316

VL - 15

SP - 53

EP - 57

JO - Journal of Information Display

JF - Journal of Information Display

IS - 2

ER -

Synthesis of blue-emitting (K _1-xNa _x)Mg ₄(PO ₄)₃:Eu ²⁺ phosphors

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this