Synthesis of HTaWO6/(Pt, TiO2) nanocomposite with high photocatalytic activities for hydrogen evolution and nitrogen monoxide destruction

Shu Yin; Daisaku Maeda; Masayuki Ishitsuka; Jihuai Wu; Tsugio Sato

doi:10.1016/S0167-2738(02)00543-X

Synthesis of HTaWO₆/(Pt, TiO₂) nanocomposite with high photocatalytic activities for hydrogen evolution and nitrogen monoxide destruction

Shu Yin, Daisaku Maeda, Masayuki Ishitsuka, Jihuai Wu, Tsugio Sato

IMRAM - Division of Inorganic Material Research

Research output: Contribution to journal › Conference article › peer-review

27 Citations (Scopus)

Abstract

HTaWO₆/(Pt, TiO₂) nanocomposite was synthesized by successive intercalation reactions of HTaWO₆ with Pt(NH₃)₄²⁺, C₃H₇NH₂/heptane mixed solution and TiO₂ acidic sol, followed by UV irradiation. The height of TiO₂ and Pt pillar is less than 0.51 nm. The host HTaWO₆ was white and possessed band gap energy of 3.11 eV, whereas the HTaWO₆/(Pt, TiO₂) nanocomposite was yellow and showed broad reflection over 400-600 nm together with that corresponding to the host layer, and possessed both excellent hydrogen evolution and nitrogen monoxide destruction photocatalytic activities even under visible light irradiation (λ>510 nm). The HTaWO₆/(Pt, TiO₂) possessed higher photocatalytic activity than those of undoped HTaWO₆, commercial titania powder (Degussa P-25), fibrous titania and Pt-doped fibrous titania.

Original language	English
Pages (from-to)	377-383
Number of pages	7
Journal	Solid State Ionics
Volume	151
Issue number	1-4
DOIs	https://doi.org/10.1016/S0167-2738(02)00543-X
Publication status	Published - 2002 Nov
Event	SSP- 2000 - Tokyo, Japan Duration: 2000 Dec 11 → 2000 Dec 13

Keywords

Hydrogen evolution
Intercalation reactions
Layered compounds
Nitrogen monoxide destruction
Semiconductors

Access to Document

10.1016/S0167-2738(02)00543-X

Cite this

@article{afa02565835c479094eedd4c0f3cae18,

title = "Synthesis of HTaWO6/(Pt, TiO2) nanocomposite with high photocatalytic activities for hydrogen evolution and nitrogen monoxide destruction",

abstract = "HTaWO6/(Pt, TiO2) nanocomposite was synthesized by successive intercalation reactions of HTaWO6 with Pt(NH3)42+, C3H7NH2/heptane mixed solution and TiO2 acidic sol, followed by UV irradiation. The height of TiO2 and Pt pillar is less than 0.51 nm. The host HTaWO6 was white and possessed band gap energy of 3.11 eV, whereas the HTaWO6/(Pt, TiO2) nanocomposite was yellow and showed broad reflection over 400-600 nm together with that corresponding to the host layer, and possessed both excellent hydrogen evolution and nitrogen monoxide destruction photocatalytic activities even under visible light irradiation (λ>510 nm). The HTaWO6/(Pt, TiO2) possessed higher photocatalytic activity than those of undoped HTaWO6, commercial titania powder (Degussa P-25), fibrous titania and Pt-doped fibrous titania.",

keywords = "Hydrogen evolution, Intercalation reactions, Layered compounds, Nitrogen monoxide destruction, Semiconductors",

author = "Shu Yin and Daisaku Maeda and Masayuki Ishitsuka and Jihuai Wu and Tsugio Sato",

year = "2002",

month = nov,

doi = "10.1016/S0167-2738(02)00543-X",

language = "English",

volume = "151",

pages = "377--383",

journal = "Solid State Ionics",

issn = "0167-2738",

publisher = "Elsevier",

number = "1-4",

note = "SSP- 2000 ; Conference date: 11-12-2000 Through 13-12-2000",

}

TY - JOUR

T1 - Synthesis of HTaWO6/(Pt, TiO2) nanocomposite with high photocatalytic activities for hydrogen evolution and nitrogen monoxide destruction

AU - Yin, Shu

AU - Maeda, Daisaku

AU - Ishitsuka, Masayuki

AU - Wu, Jihuai

AU - Sato, Tsugio

PY - 2002/11

Y1 - 2002/11

N2 - HTaWO6/(Pt, TiO2) nanocomposite was synthesized by successive intercalation reactions of HTaWO6 with Pt(NH3)42+, C3H7NH2/heptane mixed solution and TiO2 acidic sol, followed by UV irradiation. The height of TiO2 and Pt pillar is less than 0.51 nm. The host HTaWO6 was white and possessed band gap energy of 3.11 eV, whereas the HTaWO6/(Pt, TiO2) nanocomposite was yellow and showed broad reflection over 400-600 nm together with that corresponding to the host layer, and possessed both excellent hydrogen evolution and nitrogen monoxide destruction photocatalytic activities even under visible light irradiation (λ>510 nm). The HTaWO6/(Pt, TiO2) possessed higher photocatalytic activity than those of undoped HTaWO6, commercial titania powder (Degussa P-25), fibrous titania and Pt-doped fibrous titania.

AB - HTaWO6/(Pt, TiO2) nanocomposite was synthesized by successive intercalation reactions of HTaWO6 with Pt(NH3)42+, C3H7NH2/heptane mixed solution and TiO2 acidic sol, followed by UV irradiation. The height of TiO2 and Pt pillar is less than 0.51 nm. The host HTaWO6 was white and possessed band gap energy of 3.11 eV, whereas the HTaWO6/(Pt, TiO2) nanocomposite was yellow and showed broad reflection over 400-600 nm together with that corresponding to the host layer, and possessed both excellent hydrogen evolution and nitrogen monoxide destruction photocatalytic activities even under visible light irradiation (λ>510 nm). The HTaWO6/(Pt, TiO2) possessed higher photocatalytic activity than those of undoped HTaWO6, commercial titania powder (Degussa P-25), fibrous titania and Pt-doped fibrous titania.

KW - Hydrogen evolution

KW - Intercalation reactions

KW - Layered compounds

KW - Nitrogen monoxide destruction

KW - Semiconductors

UR - http://www.scopus.com/inward/record.url?scp=0036860086&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0036860086&partnerID=8YFLogxK

U2 - 10.1016/S0167-2738(02)00543-X

DO - 10.1016/S0167-2738(02)00543-X

M3 - Conference article

AN - SCOPUS:0036860086

SN - 0167-2738

VL - 151

SP - 377

EP - 383

JO - Solid State Ionics

JF - Solid State Ionics

IS - 1-4

T2 - SSP- 2000

Y2 - 11 December 2000 through 13 December 2000

ER -

Synthesis of HTaWO₆/(Pt, TiO₂) nanocomposite with high photocatalytic activities for hydrogen evolution and nitrogen monoxide destruction

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this