Synthesis of new paramagnetic heterodinuclear complexes with dithiolene bridging ligands, (Ph2C2S2)Fe(Cp1Ru)(μ-Ph2C2S2)2 (Cp1 = η5-C5H4SiMe3(CpS1), η5-C5Me5(Cp*)), by replacement of a metal fragment

Katsuaki Kuge; Shinji Inomata; Hiromi Tobita; Hiroshi Ogino

doi:10.1246/cl.1999.1075

Synthesis of new paramagnetic heterodinuclear complexes with dithiolene bridging ligands, (Ph₂C₂S₂)Fe(Cp¹Ru)(μ-Ph₂C₂S₂)₂ (Cp¹ = η⁵-C₅H₄SiMe₃(Cp^S1), η⁵-C₅Me₅(Cp*)), by replacement of a metal fragment

Katsuaki Kuge, Shinji Inomata, Hiromi Tobita, Hiroshi Ogino

Institute for Excellence in Higher Education (IEHE) (organization affiliation only)

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Thermal reactions of (Ph₂C₂S₂)₄Fe₂ with Cp¹₂Ru₂(CO)₄(Cp¹ = η⁵-C₅H₄SiMe₃, η⁵-C₅Me₅, (Cp*)) gave new paramagnetic heterodinuclear complexes (Ph₂C₂S₂)Fe(Cp¹Ru)(μ-Ph₂C₂S₂)₂ bridged by two dithiolene ligands.

Original language	English
Pages (from-to)	1075-1076
Number of pages	2
Journal	Chemistry Letters
Issue number	10
DOIs	https://doi.org/10.1246/cl.1999.1075
Publication status	Published - 1999

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Chemistry(all)

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Synthesis of new paramagnetic heterodinuclear complexes with dithiolene bridging ligands, (Ph₂C₂S₂)Fe(Cp¹Ru)(μ-Ph₂C₂S₂)₂ (Cp¹ = η⁵-C₅H₄SiMe₃(Cp^S1), η⁵-C₅Me₅(Cp*)), by replacement of a metal fragment. / Kuge, Katsuaki; Inomata, Shinji; Tobita, Hiromi et al.
In: Chemistry Letters, No. 10, 1999, p. 1075-1076.

Research output: Contribution to journal › Article › peer-review

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title = "Synthesis of new paramagnetic heterodinuclear complexes with dithiolene bridging ligands, (Ph2C2S2)Fe(Cp1Ru)(μ-Ph2C2S2)2 (Cp1 = η5-C5H4SiMe3(CpS1), η5-C5Me5(Cp*)), by replacement of a metal fragment",

abstract = "Thermal reactions of (Ph2C2S2)4Fe2 with Cp12Ru2(CO)4(Cp1 = η5-C5H4SiMe3, η5-C5Me5, (Cp*)) gave new paramagnetic heterodinuclear complexes (Ph2C2S2)Fe(Cp1Ru)(μ-Ph2C2S2)2 bridged by two dithiolene ligands.",

author = "Katsuaki Kuge and Shinji Inomata and Hiromi Tobita and Hiroshi Ogino",

year = "1999",

doi = "10.1246/cl.1999.1075",

language = "English",

pages = "1075--1076",

journal = "Chemistry Letters",

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publisher = "Chemical Society of Japan",

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T1 - Synthesis of new paramagnetic heterodinuclear complexes with dithiolene bridging ligands, (Ph2C2S2)Fe(Cp1Ru)(μ-Ph2C2S2)2 (Cp1 = η5-C5H4SiMe3(CpS1), η5-C5Me5(Cp*)), by replacement of a metal fragment

AU - Kuge, Katsuaki

AU - Inomata, Shinji

AU - Tobita, Hiromi

AU - Ogino, Hiroshi

PY - 1999

Y1 - 1999

N2 - Thermal reactions of (Ph2C2S2)4Fe2 with Cp12Ru2(CO)4(Cp1 = η5-C5H4SiMe3, η5-C5Me5, (Cp*)) gave new paramagnetic heterodinuclear complexes (Ph2C2S2)Fe(Cp1Ru)(μ-Ph2C2S2)2 bridged by two dithiolene ligands.

AB - Thermal reactions of (Ph2C2S2)4Fe2 with Cp12Ru2(CO)4(Cp1 = η5-C5H4SiMe3, η5-C5Me5, (Cp*)) gave new paramagnetic heterodinuclear complexes (Ph2C2S2)Fe(Cp1Ru)(μ-Ph2C2S2)2 bridged by two dithiolene ligands.

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 10

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Synthesis of new paramagnetic heterodinuclear complexes with dithiolene bridging ligands, (Ph₂C₂S₂)Fe(Cp¹Ru)(μ-Ph₂C₂S₂)₂ (Cp¹ = η⁵-C₅H₄SiMe₃(Cp^S1), η⁵-C₅Me₅(Cp*)), by replacement of a metal fragment

Abstract

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