Synthesis of niobium carbides from ferroniobium by mechanochemical method

Junya Kano; Solihin; Nobuaki Sato; Shigeru Suzuki; Fumio Saito; Hidetaka Suginobe; Takahiro Shiokawa

doi:10.2355/isijinternational.49.458

Synthesis of niobium carbides from ferroniobium by mechanochemical method

Junya Kano, Solihin, Nobuaki Sato, Shigeru Suzuki, Fumio Saito, Hidetaka Suginobe, Takahiro Shiokawa

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

A feasible study on a novel production process of niobium carbide (NbC) from its low cost resource ferroniobium at low temperature was examined by means of mechanochemical and subsequent chemical separation method. NbC powders as well as metallic iron (Fe) were synthesized from ferroniobium (FeNb) and graphite (C) powders by using a planetary mill at milling speed of more than 600 rpm with FeNb: C molar ratio of 1 :1. Then NbC particles were effectively separated from the mixed powders by leaching with HCI after the heat-treatment of the mixed powders in argon. These experimental results were consistent with the thermodynamic prediction.

Original language	English
Pages (from-to)	458-462
Number of pages	5
Journal	Isij International
Volume	49
Issue number	3
DOIs	https://doi.org/10.2355/isijinternational.49.458
Publication status	Published - 2009

Keywords

Ferroniobium
Mechanochemical method
Milling
Niobium carbide

ASJC Scopus subject areas

Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

Access to Document

10.2355/isijinternational.49.458

Cite this

@article{d6a5e339b6034318aca5f49e0a4ca5c1,

title = "Synthesis of niobium carbides from ferroniobium by mechanochemical method",

abstract = "A feasible study on a novel production process of niobium carbide (NbC) from its low cost resource ferroniobium at low temperature was examined by means of mechanochemical and subsequent chemical separation method. NbC powders as well as metallic iron (Fe) were synthesized from ferroniobium (FeNb) and graphite (C) powders by using a planetary mill at milling speed of more than 600 rpm with FeNb: C molar ratio of 1 :1. Then NbC particles were effectively separated from the mixed powders by leaching with HCI after the heat-treatment of the mixed powders in argon. These experimental results were consistent with the thermodynamic prediction.",

keywords = "Ferroniobium, Mechanochemical method, Milling, Niobium carbide",

author = "Junya Kano and Solihin and Nobuaki Sato and Shigeru Suzuki and Fumio Saito and Hidetaka Suginobe and Takahiro Shiokawa",

year = "2009",

doi = "10.2355/isijinternational.49.458",

language = "English",

volume = "49",

pages = "458--462",

journal = "Transactions of the Iron and Steel Institute of Japan",

issn = "0915-1559",

publisher = "Iron and Steel Institute of Japan",

number = "3",

}

TY - JOUR

T1 - Synthesis of niobium carbides from ferroniobium by mechanochemical method

AU - Kano, Junya

AU - Solihin,

AU - Sato, Nobuaki

AU - Suzuki, Shigeru

AU - Saito, Fumio

AU - Suginobe, Hidetaka

AU - Shiokawa, Takahiro

PY - 2009

Y1 - 2009

N2 - A feasible study on a novel production process of niobium carbide (NbC) from its low cost resource ferroniobium at low temperature was examined by means of mechanochemical and subsequent chemical separation method. NbC powders as well as metallic iron (Fe) were synthesized from ferroniobium (FeNb) and graphite (C) powders by using a planetary mill at milling speed of more than 600 rpm with FeNb: C molar ratio of 1 :1. Then NbC particles were effectively separated from the mixed powders by leaching with HCI after the heat-treatment of the mixed powders in argon. These experimental results were consistent with the thermodynamic prediction.

AB - A feasible study on a novel production process of niobium carbide (NbC) from its low cost resource ferroniobium at low temperature was examined by means of mechanochemical and subsequent chemical separation method. NbC powders as well as metallic iron (Fe) were synthesized from ferroniobium (FeNb) and graphite (C) powders by using a planetary mill at milling speed of more than 600 rpm with FeNb: C molar ratio of 1 :1. Then NbC particles were effectively separated from the mixed powders by leaching with HCI after the heat-treatment of the mixed powders in argon. These experimental results were consistent with the thermodynamic prediction.

KW - Ferroniobium

KW - Mechanochemical method

KW - Milling

KW - Niobium carbide

UR - http://www.scopus.com/inward/record.url?scp=67649908582&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=67649908582&partnerID=8YFLogxK

U2 - 10.2355/isijinternational.49.458

DO - 10.2355/isijinternational.49.458

M3 - Article

AN - SCOPUS:67649908582

SN - 0915-1559

VL - 49

SP - 458

EP - 462

JO - Transactions of the Iron and Steel Institute of Japan

JF - Transactions of the Iron and Steel Institute of Japan

IS - 3

ER -

Synthesis of niobium carbides from ferroniobium by mechanochemical method

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this