Synthesis of oxy aminated [60] and [70]fullerenes with cumene hydroperoxide as oxidant

Loïc Lemiègre; Takatsugu Tanaka; Takeshi Nanao; Hiroyuki Isobe; Eiichi Nakamura

doi:10.1246/cl.2007.20

Synthesis of oxy aminated [60] and [70]fullerenes with cumene hydroperoxide as oxidant

Loïc Lemiègre, Takatsugu Tanaka, Takeshi Nanao, Hiroyuki Isobe, Eiichi Nakamura

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Treatment of [60] or [70]fullerene with excess secondary amine and 3 equiv. of cumene hydroperoxide regioselectively afforded a mono-oxygenated tetraamino or diamino fullerene in good to high yield. The reaction is operationally simple and applicable to a large-scale synthesis.

Original language	English
Pages (from-to)	20-21
Number of pages	2
Journal	Chemistry Letters
Volume	36
Issue number	1
DOIs	https://doi.org/10.1246/cl.2007.20
Publication status	Published - 2007 Jan 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2007.20

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abstract = "Treatment of [60] or [70]fullerene with excess secondary amine and 3 equiv. of cumene hydroperoxide regioselectively afforded a mono-oxygenated tetraamino or diamino fullerene in good to high yield. The reaction is operationally simple and applicable to a large-scale synthesis.",

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AU - Lemiègre, Loïc

AU - Tanaka, Takatsugu

AU - Nanao, Takeshi

AU - Isobe, Hiroyuki

AU - Nakamura, Eiichi

PY - 2007/1/5

Y1 - 2007/1/5

N2 - Treatment of [60] or [70]fullerene with excess secondary amine and 3 equiv. of cumene hydroperoxide regioselectively afforded a mono-oxygenated tetraamino or diamino fullerene in good to high yield. The reaction is operationally simple and applicable to a large-scale synthesis.

AB - Treatment of [60] or [70]fullerene with excess secondary amine and 3 equiv. of cumene hydroperoxide regioselectively afforded a mono-oxygenated tetraamino or diamino fullerene in good to high yield. The reaction is operationally simple and applicable to a large-scale synthesis.

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Synthesis of oxy aminated [60] and [70]fullerenes with cumene hydroperoxide as oxidant

Abstract

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