Synthesis of surface nitride on Pd(100) surface by a reaction of NO with H2

Iwao Matsuo; Junji Nakamura; Hideki Hirano; Taro Yamada; Ken Ichi Tanaka; Kenzi Tamaru

Synthesis of surface nitride on Pd(100) surface by a reaction of NO with H₂

Iwao Matsuo, Junji Nakamura, Hideki Hirano, Taro Yamada, Ken Ichi Tanaka, Kenzi Tamaru

Research output: Contribution to journal › Article › peer-review

Abstract

A c(2×2) overlayer of surface nitride was for the first time synthesized on Pd(100) surface by a catalytic reaction of NO + H₂ → [N] + H₂O at several Torr of total pressure at 500-600 K. Pure c(2×2) surface nitride on Pd(100) surface is stable up to about 600 K in vacuum but reacts readily with H₂ at 10^-6-10^-9 Torr to give NH₃ at 440 K, that is, c(2×2)-N is an intermediate compound of the NH₃ formation reaction.

Original language	English
Pages (from-to)	7747-7749
Number of pages	3
Journal	Journal of physical chemistry
Volume	93
Issue number	23
Publication status	Published - 1989 Dec 1
Externally published	Yes

ASJC Scopus subject areas

Engineering(all)
Physical and Theoretical Chemistry

Cite this

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title = "Synthesis of surface nitride on Pd(100) surface by a reaction of NO with H2",

abstract = "A c(2×2) overlayer of surface nitride was for the first time synthesized on Pd(100) surface by a catalytic reaction of NO + H2 → [N] + H2O at several Torr of total pressure at 500-600 K. Pure c(2×2) surface nitride on Pd(100) surface is stable up to about 600 K in vacuum but reacts readily with H2 at 10-6-10-9 Torr to give NH3 at 440 K, that is, c(2×2)-N is an intermediate compound of the NH3 formation reaction.",

author = "Iwao Matsuo and Junji Nakamura and Hideki Hirano and Taro Yamada and Tanaka, {Ken Ichi} and Kenzi Tamaru",

year = "1989",

month = dec,

day = "1",

language = "English",

volume = "93",

pages = "7747--7749",

journal = "Journal of Physical Chemistry",

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publisher = "American Chemical Society",

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T1 - Synthesis of surface nitride on Pd(100) surface by a reaction of NO with H2

AU - Matsuo, Iwao

AU - Nakamura, Junji

AU - Hirano, Hideki

AU - Yamada, Taro

AU - Tanaka, Ken Ichi

AU - Tamaru, Kenzi

PY - 1989/12/1

Y1 - 1989/12/1

N2 - A c(2×2) overlayer of surface nitride was for the first time synthesized on Pd(100) surface by a catalytic reaction of NO + H2 → [N] + H2O at several Torr of total pressure at 500-600 K. Pure c(2×2) surface nitride on Pd(100) surface is stable up to about 600 K in vacuum but reacts readily with H2 at 10-6-10-9 Torr to give NH3 at 440 K, that is, c(2×2)-N is an intermediate compound of the NH3 formation reaction.

AB - A c(2×2) overlayer of surface nitride was for the first time synthesized on Pd(100) surface by a catalytic reaction of NO + H2 → [N] + H2O at several Torr of total pressure at 500-600 K. Pure c(2×2) surface nitride on Pd(100) surface is stable up to about 600 K in vacuum but reacts readily with H2 at 10-6-10-9 Torr to give NH3 at 440 K, that is, c(2×2)-N is an intermediate compound of the NH3 formation reaction.

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M3 - Article

AN - SCOPUS:0242594662

SN - 0022-3654

VL - 93

SP - 7747

EP - 7749

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 23

ER -

Synthesis of surface nitride on Pd(100) surface by a reaction of NO with H₂

Abstract

ASJC Scopus subject areas

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