Synthesis of titania-pillared hydrogen tetratitanate nanocomposites and control of slit width

M. Yanagisawa; S. Uchida; S. Yin; T. Sato

doi:10.1021/cm000335f

Synthesis of titania-pillared hydrogen tetratitanate nanocomposites and control of slit width

M. Yanagisawa, S. Uchida, S. Yin, T. Sato

IMRAM - Division of Inorganic Material Research

Tohoku University

Research output: Contribution to journal › Article › peer-review

69 Citations (Scopus)

Abstract

Slit-width-controlled H₂Ti₄O₉/TiO₂ nanocomposites were fabricated by stirring with (C_nH_2n+1NH₃)₂ Ti₄O₉ and a titanyl acylate complex at 20 °C for 48 h followed by UV light irradiation from a 450 W high-pressure mercury lamp. (C_nH_2n+1NH₃)₂Ti₄ O₉ was synthesized by an intercalation reaction with H₂Ti₄O₉ and C_nH_2n+1NH₂ in aqueous or heptane solution for 48 h. The remaining C_nH_2n+1NH₂ and acylate after titania incorporation was completely decomposed into CO₂, H₂O, and NH₃ by UV light irradiation. A slit in the obtained nanocomposites was produced, and its width could be controlled by changing the carbon length of C_nH_2n+1NH₂. Furthermore, the slit expansion and the transformation of the layer structure to fiberlike TiO₂ were successfully confirmed by scanning electron microscopy photographs for the first time.

Original language	English
Pages (from-to)	174-178
Number of pages	5
Journal	Chemistry of Materials
Volume	13
Issue number	1
DOIs	https://doi.org/10.1021/cm000335f
Publication status	Published - 2001

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10.1021/cm000335f

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title = "Synthesis of titania-pillared hydrogen tetratitanate nanocomposites and control of slit width",

abstract = "Slit-width-controlled H2Ti4O9/TiO2 nanocomposites were fabricated by stirring with (CnH2n+1NH3)2 Ti4O9 and a titanyl acylate complex at 20 °C for 48 h followed by UV light irradiation from a 450 W high-pressure mercury lamp. (CnH2n+1NH3)2Ti4 O9 was synthesized by an intercalation reaction with H2Ti4O9 and CnH2n+1NH2 in aqueous or heptane solution for 48 h. The remaining CnH2n+1NH2 and acylate after titania incorporation was completely decomposed into CO2, H2O, and NH3 by UV light irradiation. A slit in the obtained nanocomposites was produced, and its width could be controlled by changing the carbon length of CnH2n+1NH2. Furthermore, the slit expansion and the transformation of the layer structure to fiberlike TiO2 were successfully confirmed by scanning electron microscopy photographs for the first time.",

author = "M. Yanagisawa and S. Uchida and S. Yin and T. Sato",

year = "2001",

doi = "10.1021/cm000335f",

language = "English",

volume = "13",

pages = "174--178",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

number = "1",

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T1 - Synthesis of titania-pillared hydrogen tetratitanate nanocomposites and control of slit width

AU - Yanagisawa, M.

AU - Uchida, S.

AU - Yin, S.

AU - Sato, T.

PY - 2001

Y1 - 2001

N2 - Slit-width-controlled H2Ti4O9/TiO2 nanocomposites were fabricated by stirring with (CnH2n+1NH3)2 Ti4O9 and a titanyl acylate complex at 20 °C for 48 h followed by UV light irradiation from a 450 W high-pressure mercury lamp. (CnH2n+1NH3)2Ti4 O9 was synthesized by an intercalation reaction with H2Ti4O9 and CnH2n+1NH2 in aqueous or heptane solution for 48 h. The remaining CnH2n+1NH2 and acylate after titania incorporation was completely decomposed into CO2, H2O, and NH3 by UV light irradiation. A slit in the obtained nanocomposites was produced, and its width could be controlled by changing the carbon length of CnH2n+1NH2. Furthermore, the slit expansion and the transformation of the layer structure to fiberlike TiO2 were successfully confirmed by scanning electron microscopy photographs for the first time.

AB - Slit-width-controlled H2Ti4O9/TiO2 nanocomposites were fabricated by stirring with (CnH2n+1NH3)2 Ti4O9 and a titanyl acylate complex at 20 °C for 48 h followed by UV light irradiation from a 450 W high-pressure mercury lamp. (CnH2n+1NH3)2Ti4 O9 was synthesized by an intercalation reaction with H2Ti4O9 and CnH2n+1NH2 in aqueous or heptane solution for 48 h. The remaining CnH2n+1NH2 and acylate after titania incorporation was completely decomposed into CO2, H2O, and NH3 by UV light irradiation. A slit in the obtained nanocomposites was produced, and its width could be controlled by changing the carbon length of CnH2n+1NH2. Furthermore, the slit expansion and the transformation of the layer structure to fiberlike TiO2 were successfully confirmed by scanning electron microscopy photographs for the first time.

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DO - 10.1021/cm000335f

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JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 1

ER -

Synthesis of titania-pillared hydrogen tetratitanate nanocomposites and control of slit width

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